A lyotropic AgNO3, HAuCl4 and H2PtCl6–silica liquid crystalline (LC) phase is used as a supramolecular template for a one-pot synthesis of novel noble metal or complex ion containing nanocomposite materials in the form of a film and monolith. In these structures, Ag, AuCl4 2 and PtCl6 22 ions interact with the head group of an oligo(ethylene oxide) type non-ionic surfactant (C12H25(CH2CH2O)10OH...

Alkali metals and their alloys can be protected from spontaneous reaction with dry air by intercalation (with subsequent heating) into the pores of silica gel (SG) at loadings up to 40 wt %. The resulting loose, black powders are convenient materials for chemical reduction of organic compounds and the production of clean hydrogen. The problem addressed in this paper is the nature of the reducin...

Based upon the statistical distribution of flexural fatigue life data and flexural fatigue strength of the steel fibre reinforced concrete (SFRC) containing blends of limestone powder (LP) and silica fume (SF), the influence of these inserts on the flexural fatigue performance of concretes is probed. Concrete mixes were proportioned to replace 30% cement with these mineral inserts in different ...

the gas separation performance of commercial ceramic titania and hybrid silica (hybsi®) membranes was assessed using the gas permeation and permporometry methods. results indicated that the hybsi® membranes have a hybrid surface containing regions covered by a polymeric matrix and others with inorganic pores. these membranes have high h2 selectivity, which increases significantly with temperatu...

In an effort to understand the various phenomena which occur during aging of silica gels at different pH, silica particles prepared by three routes distinguished principally by their silicon coordination (Qn distributions) (St6ber silica spheres, Ludox and Cab-O-Sil) were employed. In situ techniques were used including proton spin-latt ice relaxation, SAXS and zeta potential for the wet state ...