Interfacial diffusion is of great importance in determining the performance of solid-state reactions. For nanometer sized particles, some solid-state reactions can be triggered accidently by mechanical stress owing to their large surface-to-volume ratio compared with the bulk ones. Therefore, a great challenge is the control of interfacial diffusion for solid state reactions, especially for ene...

We demonstrate a simple strategy to either prevent or enhance hydroxide incorporation in nanocrystalline solid-state metathesis reaction products prepared in ambient environments. As an example, we show that ZnCO3 (smithsonite) or Zn₅(CO₃)₂(OH)₆ (hydrozincite) forms extremely rapidly, in less than two minutes, to form crystalline domains of 11 ± 2 nm and 6 ± 2 nm, respectively. The phase select...

In this research, zeolite-TiO2 nanocomposite was prepared for degradation of dibenzothiophene as a typical aromatic organosulfur compound of transportation fuels.The synthesized TiO2 was immobilized on the surface of clinoptilolite by Solid State Dispersion (SSD) method. The nanocomposite was then characterized by XRD, FTIR, TEM and SEM techniques. Photodegradation of ...

Rechargeable magnesium batteries have attracted considerable attention because of their potential high energy density and low cost. However, their development has been severely hindered because of the lack of appropriate cathode materials. Here we report a rechargeable magnesium/iodine battery, in which the soluble iodine reacts with Mg2+ to form a soluble intermediate and then an insoluble fin...

the direct sulfation of three high purity iranian limestones and one precipitated calcium carbonate from different sources, containing more than 97 % caco3, were studied in a specially designed fixed bed reactor under atmospheric pressure, in the presence of excess co2 to prevent decomposition of caco3. experiments were carried out over a range of particle sizes from 1.6-2.5  mm at four tempera...

a two-dimensional cfd model of a planar solid oxide fuel cell (sofc) has been developed.this model can predict the performance of sofc at various operating and design conditions.the effect of knudsen diffusion is accounted in the porous electrode (backing) and reaction zonelayers. the mathematical model solves conservation of electrons and ions and conservation ofspecies. the model is formulate...

Reaction zones formed at 790 °C between solid titanium and liquid Ag-Cu eutectic alloys (pure and Ti-saturated) have been characterized. When pure Ag-Cu eutectic alloy with 40 at.% Cu is used, the interface reaction layer sequence is: αTi / Ti2Cu / TiCu / Ti3Cu4 / TiCu4 / L. Because of the fast dissolution rate of Ti in the alloy, the reaction zone remains very thin (3-6 μm) whatever the reacti...

objectives: the aim of this study was to compare the permeability of dentin after using diamond bur and er:yag laser. materials and methods: seventy-two recently extracted, intact, and restoration-free human permanent molars were used in this study. the samples were randomly divided into three groups of 24 each and class i cavities were prepared as follows. group 1: high speed diamond bur with ...

introduction: male urethral stricture is a complicated urologic disease that could be successfully treated using internal urethrotomy. laser internal urethrotomy has been used in many cases with favorable outcome in many studies. holmium: yag laser with its incisional properties on tissue is one of the laser types applied for internal urethrotomy. methods: we present a 19 year-old male with his...