the acid-base equilibrium of lorazepam was studied by means of potentiometry andmultiwavelengths spectrophotometry. the stoichiometric equilibrium constants were determinedat 25 °c and constant ionic strength 0.1 mol l-1 (nacl). the acidity constants pk1=1.58±0.05and pk2=11.67±0.07 were found by potentiometry, and pk1=1.54±0.02 and pk2=11.61±0.03 bymulti-wavelengths spectrophotometry. potentiom...

The technique of spectroscopic ellipsometry is a powerful tool for the characterization optical properties materials. This represents significant refinement over semi-empirical approach to constants determination using BRDF (Bidirectional Reflectance Distribution Function) measurements finite set grain sizes each mineral. It also allows obtaining, not only constants, but information about depen...

Abstract The temperature dependence of the optical constants materials (refractive index, absorption and extinction coefficients, dielectric function) can be determined with spectroscopic ellipsometry over a broad range temperatures photon energies or wavelengths. Such results have practical value, for example applications at cryogenic elevated temperatures. gaps their broadenings also provides...

Remotely keyed encryption (RKE) schemes provide fast symmetric encryption and decryption using a small-bandwidth security module and a powerful host. Such schemes keep the key inside the security module to prevent key compromise. Shin, Shin, and Rhee proposed a length-preserving as well as a length-increasing RKE scheme that both use only a single round of interaction between host and security ...

VUV photoionization dynamics of the S2 molecule were re-investigated from threshold up to 15.0 eV, using synchrotron radiation coupled with double imaging photoelectron/photoion coincidence featuring high resolution capabilities. We measured first photoelectron spectrum achieving higher than previous literature derive accurate spectroscopic constants for a few electronic states cation including...

Using an ab initio approach involving a non-empirical pseudopotentials for Na and Rb atoms, the adiabatic potential energy curves of 26 electronic states of NaRb ionic molecule dissociating up to Na(4p) + Rb and Na + Rb(7s) have been investigated. Their molecular spectroscopic constants have been derived and compared with the available theoretical works. Furthermore, the transition dipole momen...

The binding of sinafloxacin to DNA has been studied by fluorescence spectroscopy and UV-vis absorption spectroscopy. The variations in the spectroscopic characteristics of sinafloxacin upon addition of DNA were observed. Salt concentration effect, KI quenching, fluorescence polarization, DNA denaturation experiments, melting temperature (T(m)) curves and viscosity measurements were studied to i...

The solvatochromic responses of uric acid (Ua), 6-amino-2-thiouracil (ATU) and a series of their complexes dissolved in ten solvents of different polarity have been measured. The solvent-dependent UV/Vis spectroscopic absorption maxima, λ(max), are assigned to the corresponding electronic transitions and analyzed using SPSS program, regression analysis and Kamlet and Taft methods. The observed ...