The switch from a carbon-based to hydrogen-based economy requires environmentally friendly methods for hydrogen production. CO 2 -reforming of methane promises be greener alternative steam-methane reforming, which accounts the majority production today. For this dry process become industrially competitive, challenges such as catalyst deactivation and degradation through coke formation must bett...

Thermodynamic analysis of the cracking of hexane has been conducted by the Gibbs free energy minimization method and second law analysis of overall reactions. By-products have been divided into three groups of methane, alkynes and aromatics and their possible production paths have been discussed. Effect of operating conditions such as temperature and steam-to-hexane ratio on the cracking perfor...

Two pretreatment methods, microwave irradiation and steam explosion, were investigated in this work. The aim of the study was to investigate whether these methods would improve the biodegradability of wheat straw as a lignocellulosic feedstock. Microwave pretreatment was carried out on milled straw with an irradiation time of 15 minutes, at a temperature of either 200 or 300 °C in the oven. The...

Hydrothermal, dilute acid, and steam explosion pretreatment methods, were evaluated for their efficiency to improve the methane production yield of three Mediterranean agricultural lignocellulosic residues such as olive tree pruning, grapevine pruning, and almond shells. Hydrothermal and dilute acid pretreatments provided low to moderate increase in the digestibility of the biomass samples, whe...

In this work, a reliable kinetic reaction mechanism was revised to accurately reproduce the detailed paths of steam reforming methane over Ni/Al2O3 catalyst. A steady-state fixed-bed reactor experiment and 1D catalyst model were utilized for task. The distinctive feature is possibility measure axially resolved temperature profile bed, which makes kinetics inside visible. This allows understandi...

As a favorably clean fuel, syngas (synthesis gas) production has been the focus of concern in past decades. Substantial literatures reported the syngas production by various catalytic reforming reactions particularly in methane or ethanol reforming. Among the developed catalysts in these reforming processes, Ni-based catalysts from hydrotalcite-like compounds (HTLcs) precursors have drawn consi...

The conversion of logistics fuels to hydrogen by steam reforming is attractive but poses great challenge since they contain sulfur up to about 3000 ppm leading to catalyst deactivation due to sulfur poisoning. In this paper, we report the fabrication of nominally doped nanoscale ceriasupported rhodium catalyst matrices for their performance evaluation in sulfur-laden fuel streams. Systematic st...

A simple yet efficient method to remove organic ligands from supported nanocrystals is reported for activating uniform catalysts prepared by colloidal synthesis procedures. The method relies on a fast thermal treatment in which ligands are quickly removed in air, before sintering can cause changes in the size and shape of the supported nanocrystals. A short treatment at high temperatures is fou...

A comprehensive mathematical model of the performance of the cathode-supported solid oxide fuel cell (SOFC) with syngas fuel is presented. The model couples the intricate interdependency between the ionic conduction, electronic conduction, gas transport, the electrochemical reaction processes in the functional layers and on the electrode/electrolyte interfaces, methane steam reforming (MSR) and...