Thin films of stable metal-organic frameworks (MOFs) such as UiO-66 have enormous application potential, for instance in microelectronics. However, all-gas-phase deposition techniques are currently not available for such MOFs. We here report on thin-film deposition of the thermally and chemically stable UiO-66 in an all-gas-phase process by the aid of atomic layer deposition (ALD). Sequential r...

This study was aimed to evaluate the correlation between in vitro fermentation and in situ degradation parameters and to predict dry matter degradability and energy protein synchronization of roughage based diets. Different inclusion of roughage in diets [roughage 50% diet (R50D), roughage 60% diet (R60D), roughage 65% diet (R65D) and roughage ...

In this work, the dry reforming of methane was studied using a corona and gliding discharge plasma microreactors. A chemical kinetic model was developed to describe the experimental behavior observed. The kinetic model is proposed based on the assumption that the reactant molecules CH4 or CO2 are attacked by active species produced b...

One-dimensional a-Fe2O3 is a promising nanomaterial for advanced applications in catalysis and water splitting, environmental protection, sensors, dye solar cells, magnetic storage media, bioprocessing, and controlled drug delivery and detection, especially as carriers of antigens for prion detection and PCR manipulation. a-Fe2O3 nanowires have been successfully synthesized by various methods b...

Microcystis aeruginosa is a planktonic unicellular cyanobacterium often responsible for seasonal mass occurrences at the surface of freshwater environments. An abundant production of intracellular structures, the gas vesicles, provides cells with buoyancy. A 8.7-kb gene cluster that comprises twelve genes involved in gas vesicle synthesis was identified. Ten of these are organized in two operon...

1. Introduction In this work, we utilized molecular dynamics simulations to investigate gas diffusion in realistic nanoporous carbon models. We will focused on how the structure of the porous medium affects the gas diffusion. The porous structural features of interests include topological defects, dangling bonds, size and connectivity of the pores. Through a mimetic virtual synthesis routine, p...

The shift of paradigm in combinatorial chemistry, from large compound libraries (of mixtures) on a small scale towards defined compound libraries where each compound is prepared in an individual well, has stimulated the search for alternative separation approaches. The key to a rapid and efficient synthesis is not only the parallel arrangement of reactions, but simple work-up procedures so as t...

Ecological aspects of coal combustion utilization of CO2 from flue gas Slovakia belongs to the group of twenty worst polluters throughout the world, releasing 10 12 tons of carbon dioxide per capita, whereas the worldwide average value is about 5 tons. It is known that the big electric and thermal power stations produce only 25 % of the overall production of carbon dioxide in Slovakia, whereas ...

Work in 2012-2013 focused on studying gas permeability, diffusivity and solubility of polyimides and thermally rearranged (TR) polymers based on 3,3’-dihydroxy-4,4’diaminobiphenyl (HAB) and 2,2’-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA). To determine the effect of temperature on gas sorption, we studied H2 sorption in the HAB-6FDA polyimide and 3 partially converted HAB-6FD...

Many engineering applications require carbon nanotubes with specific characteristics such as wall structure, chirality and alignment. However, precise control of nanotube properties grown to application specifications remains a significant challenge. Plasma-enhanced chemical vapor deposition (PECVD) offers a variety of advantages in the synthesis of carbon nanotubes in that several important sy...