Attempts to synthesize solvent-free MgB12H12 by heating various solvated forms (H2O, NH3, and CH3OH) of the salt failed because of the competition between desolvation and dehydrogenation. This competition has been studied by thermogravimetric analysis (TGA) and temperature-programmed desorption (TPD). Products were characterized by IR, solution- and solid-state NMR spectroscopy, elemental analy...

abstract: two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (h2l5), and 1,10-phenanthroline（phen） and 1,3-di(4-pyridyl)propane (bpp) as secondary ligands are reported. they are formulated as {[pb(hl5)2(phen)(h2o)]·h2o}n(1), [zn2(hl5)4(bpp)2]n(2). all the complexes are characterized by single-crystal x-ray diffractions. compoud 1 crystallizes in the triclini...

Very limited experimental data are available on thermal decomposition of germane in the gas phase. Recent developments in theoretical quantum chemistry techniques such as ab initio Hartree-Fock and density functional methods have made accurate determination of molecular properties possible. Systematic development of a detailed gas-phase decomposition mechanism for germane using ab initio molecu...

9 Co-first authors who contributed equally to this work. 10 11 *Corresponding author: 12 Yahai Lu 13 College of Resources and Environmental Sciences, 14 China Agricultural University 15 Beijing 100193, China 16 Phone: +86-10-62733617; Fax: +86-10-62733617 17 Email: [email protected] 18 19 Running title: Syntrophic propionate oxidation in rice field soil 20

Thermal decomposition and kinetics behaviour of the de-oiled seed cake of African star apple (Chrosophyllum albidum) has been investigated using thermogravimetry under the nitrogen atmosphere from ambient temperature to 900 °C. The thermogravimetric data for the cake decomposition at six different heating rates (5, 10, 15, 20, 30 and 40 °C/min) were used to evaluate the kinetic decomposition of...

Thermal stability studies on some metal soaps of Hura crepitans seed oil prepared by metathesis in aqueous alcohol solution were carried out. The kinetics of the decomposition was studied thermogravimetrically in the temperature range 160 – 200 C. The values of the rate constant are of the order 10min and temperature-dependent. The enthalpy of activation (∆H) of the initial stage of decompositi...

The high-temperature (HT) phase of Y(BH(4))(3) has been prepared by heating of the as mechanochemically synthesised low-temperature (LT) phase of Y(BH(4))(3) to 194-216 °C and subsequent rapid cooling to ambient temperature. Although the differences in the crystal structure and vibrational spectra for these closely-related polymorphs are rather small, yet the NMR MAS (1)H and CP MAS (89)Y spect...