The title compound, C(14)H(12)N(2), was synthesized by the reaction of 4-methyl-N-(2-nitro-benz-yl)aniline with tin(II) chloride dihydrate in ethanol at 313 K. The indazole ring system is almost planar with a dihedral angle of 1.58 (10)° between the rings, whereas the plane of the attached p-tolyl substituent shows a dihedral angle of 46.26 (5)° with respect to the indazole core.

2,5-Dideoxy-2,5-imino-D-glucitol (DGDP) has been synthesized via the tin(II)-mediated anti-selective aldol reaction of bislactim ether 5 and a 3-O-silylated 2,4-ethylidene-D-erythrose derivative 6. In accordance with density functional theory calculations (at the B3LYP/cc-pVDZ-PP level), pericyclic transition structures with a boat-like conformation and a stabilizing hydrogen bond can account f...

The new potential tracer of bone imaging, AHBDP-Sn(II)-TcO.3H(2)O was synthesized by reducing the TcO(4) (-) to TcO(2) (+) in the presence of AHBDP and Sn(ll)'s reducing agent. We found that tin rapidly forms a stable complex with AHBDP, giving AHBDP-Sn(II).3H(2)O. In the excess of AHBDP-Sn(ll).3H(2)O, the AHBDP-Sn(II).3H(2)O coordinates with TcO(2) (+) to give AHBDP-Sn(II)-TcO.3H(2)O which cou...

Most foods contain very low concentrations of tin, usually below 10 mg/kg, although canned foods may contain higher concentrations as a result of the slow dissolution of the tin coating used on the inside of some food cans to protect the steel body of the can from corrosion. An inductively coupled plasma-mass spectrometry (ICP-MS) method following microwave digestion was developed and evaluated...

Chromosome instability has a pivotal role among the hallmarks of cancer, but its transcriptional counterpart is rarely considered a relevant factor in cell destabilization. To examine transcription instability (TIN), we first devised a metric we named TIN index and used it to evaluate TIN on a dataset containing more than 500 neuroblastoma samples. We found that metastatic tumors from high-risk...

Article history: Received 28 September 2015 Revised 2 December 2015 Accepted in revised form 11 December 2015 Available online 12 December 2015 A three-layer backward propagation (BP)modelwas used to predict the hardness of Ni–TiNnanocoatings fabricated by pulse electrodeposition. The effect of plating parameters, namely, TiN particle concentration, current density, pulse frequency, and duty ra...

The movement to eliminate lead (Pb), especially active in Japan and the European Union, has resulted in an increasing use of pure tin (Sn) coatings on leads and other external and internal surfaces of capacitors, resistors, and other passive components. This paper discusses the issues of tin whisker growth with respect to passive components. It also presents both a critical analysis of existing...

Pyridobenzimidazoles 6a-iwere synthesized in very good to excellent yields (81-96%) by the condensation of substituted N-phenyl-o-phenylenediamines 4a-d with indole/benzo[b]thiophene-3-aldehydes 5a-t inmethoxyethanol under reflux conditions. The diamines 4a-d were prepared byfirst treating 2-chloro-3-nitropyridine (1)with suitably substituted anilines 2a-d then reducing the resulting3-nitro-N-p...

pure and antimony doped sno2 thin films have been prepared by the sol-gel dip coating technique on glass substrate using starting material sncl2.2h2o as a host and sbcl3 as a dopant. our experimental results revealed that, the quality of the coated films on the glass depends on process parameters. the effect of annealing temperature, dipping numbers and the dopant concentration on the structura...