In this study, the optical properties of a TiO2 photocatalyst were enhanced with various impregnations of Er3+ and Ni2+ separately, using the impregnation method as photocatalysts for the direct solar photolysis degradation of chloroxylenol. The synthesized Er/TiO2 and Ni/TiO2 catalysts were characterized using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy...

A few-layered CDs (carbon dots)/MoS2 nanosheet-coated hydrogenated TiO2 (H-TiO2) nanobelt heterostructures—referred to as CDs/MoS2@H-TiO2—with a flexible three-dimensional (3D) hierarchical configuration were prepared via a facial hydrothermal reaction. Note that the visible photocatalytic activity of H-TiO2 was improved compared with that of pristine rutile TiO2, which can be mainly attributed...

A hybrid photocatalyst based on anatase TiO2 was designed by doping TiO2 with sulfur and incorporating reduced graphene oxide (TiO2-S/rGO hybrid), with an aim to narrow the band gap to potentially make use of visible light and decrease the recombination of excitons, respectively. This TiO2-S/rGO hybrid was successfully synthesized using a one-pot hydrothermal method via single-step reaction. Th...

TiO2 nanotubes attract much attention because of their high photoelectron-chemical and photocatalytic efficiency. But their large band gap leads to a low absorption of the solar light and limits the practical application. How to obtain TiO2 nanotubes without any dopant and possessing visible light response is a big challenge nowadays. Orthorhombic titanic acid nanotubes (TAN) are a special prec...

Au-TiO2 nanocomposites were prepared by chemical deposition of gold nanoparticles onto TiO2 nanocolloids that were synthesized by a hydrothermal method. Transmission electron microscopic measurements showed that the TiO2 colloids exhibited an average diameter of about 5 nm and clearly defined lattice fringes that were consistent with those of anatase TiO2 and formed rather large agglomerates th...

Pristine TiO2/Au (P-TiO2/Au) is modified by hydrogen plasma (H-TiO2/Au) or and oxygen (H-O-TiO2/Au) treatment, then used as electrochemical catalysts for nitrogen reduction reaction (NRR). H-TiO2/Au shows enhanced performance the NRR process compared with both P-TiO2/Au H-O-TiO2/Au. After hydrogenation some disordered regions on surface of TiO2 nanoparticles are formed, a large number vacancies...

A comparison between Au, TiO2 and self-catalysed growth of SnO2 nanostructures using chemical vapour deposition is reported. TiO2 enables growth of a nanonetwork of SnO2 , whereas self-catalysed growth results in nanoclusters. Using Au catalyst, single-crystalline SnO2 nanowire trees can be grown in a one-step process. Two types of trees are identified that differ in size, presence of a catalyt...

Laboratory experiments have been performed to investigate photocatalytic detoxification by using TiO2 photocatalyst for treating dairy effluent. Various operational parameters such as catalyst concentration, initial concentration, angle of tilt of solar flat plate reactor and flow rate were investigated. Results indicated that the photocatalytic detoxification process can efficiently treat dair...

Catalyst stability in the liquid phase under polar conditions, typically required for the catalytic conversion of renewable platform molecules, is a major concern but has been only sparsely studied. Here, the activity, selectivity, and stability of Ru-based catalysts supported on TiO2, ZrO2, and C in the conversion of levulinic acid (LA) to γ-valerolactone (GVL) has been studied at 30 bar of H2...

When Au is subdivided to the nanoscale its reactivity changes from an inert nature to one of incredible reactivity which is not replicated by other catalysts. When dispersed onto metal oxides such as TiO2, nano-Au has shown high reactivities for a multitude of reduction and oxidation reactions of industrial importance with potential and current uses such as, CO oxidation, NO x reduction, purifi...