First order phase transitions are described in terms of the microcanonical and canonical ensemble, with special attention to finite size effects. Difficulties in interpreting a " caloric curve " are discussed. A robust parameter indicating phase coexistence (univariance) or single phase (bivariance) is extracted for charge distributions. 1 Phase transitions, phase coexistence, and charge distri...

Polyaniline fiber is a promising biosensor material due to the capability of this material as an effective mediator for electron transfer. The polyaniline in fibre has wider surface to increase the electron transfer. In this work, polyaniline structure synthesized by interfacial polymerization was compared to polyaniline structure obtained from electrospinning to get a better fibre structure. I...

Fluids in which the interparticle potential has a hard core, is attractive at moderate separations, and repulsive at large separations are known to exhibit unusual phase behavior, including stable inhomogeneous phases. Here we report a joint simulation and theoretical study of such a fluid, focusing on the relationship between the liquid-vapor transition line and any new phases. The phase diagr...

The solution of a boundary–value problem formulated for a modified Kretschmann configuration shows that the phase speed of a surface–plasmon wave guided by the planar interface of a sufficiently thin metal film and a chiral sculptured thin film (STF) depends on the vapor incidence angle used while fabricating the chiral STF by physical vapor depoistion. Therefore, it may be possible to engineer...

The phase diagram of a simple model with two patches of type A and ten patches of type B (2A10B) on the face centred cubic lattice has been calculated by simulations and theory. Assuming that there is no interaction between the B patches the behavior of the system can be described in terms of the ratio of the AB and AA interactions, r. Our results show that, similarly to what happens for relate...

Polycyclic aromatic hydrocarbons (PAH) are ubiquitous pollutants resulting from incomplete combustion and many fuel processing and storage operations. They are encountered in the environment in many forms, ranging from non-aqueous phase liquid and/or solid mixtures (i.e., NAPL and NAPS materials), to dissolved aqueous phase components, to adsorbed species on solid surfaces. The present work con...

Ultrathin coatings of fluorosilane films for silicon and polydimethylsiloxane PDMS nanochannels are desirable to control the hydrophobicity of the surface and reduce or prevent undesired protein adsorption or cell interactions critical for the performance of most biomedical micro/nanodevices. Surface modifications using vapor-phase deposition become increasingly important for some biomedical na...

The aspects of the proposed vapor clearing and condensation experiment involve rapidly generating an IFE prototypical post-shot vapor density in a control volume using characteristic liquid chamber material (FliBe, Li2BeF4), and investigating the condensation rates for the proposed schemes. This experimental goal is achieved by: 1) a pulsed electrothermal plasma source that simulates the pellet...

Recent studies have pointed to olfactory system beta oscillations of the local field potential (15-30 Hz) and their roles both in learning and as specific responses to predator odors. To describe odorant physical properties, resultant behavioral responses and changes in the central olfactory system that may induce these oscillations without associative learning, we tested rats with 26 monomolec...

Ion-selective electrode (ISE) based potentiometric gas sensors have shown to be promising analytical tools for detection of chemical vapors. However, such sensors are only capable of detecting those vapors which can be converted into ionic species in solution. This paper describes for the first time a polymer membrane ISE based potentiometric sensing system for sensitive and selective determina...