نتایج جستجو برای: weak separation
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In the title compound, C(15)H(11)BrO(3), the dihedral angle between the naphtho-furan ring system (r.m.s. deviation = 0.022 Å) and the side chain is 4.50 (2)°. In the crystal, short Br⋯Br [3.4435 (7) Å] contacts propagating along [010] in a zigzag manner and weak π-π inter-actions [shortest centroid-centroid separation = 3.573 (2) Å] directedalong [100] are observed.
In the title compound, C(14)H(12)N(2)O(4)S, the dihedral angle between the two aromatic rings is 35.65 (12)°. The crystal packing is stabilized by weak C-H⋯O hydrogen bonds and aromatic π-π ring stacking inter-actions [minimum ring centroid separation = 3.697 (3) Å].
The mol-ecule of the title compound, C(8)H(6)N(4)S, is almost planar [maximum deviation from the mean plane = 0.020 (1) Å for the S atom]. In the crystal, a supra-molecular three-dimensional arrangement arises from N-H⋯N hydrogen bonds and weak aromatic stacking interactions along the a axis [centroid-centroid separation = 3.582 (2) Å].
The exceptional resolution of UVES has allowed the detection of weak spectral features and the separation of components in blended lines. The intensities of all of the OIII fluorescence lines produced by the O1, O3 and other channels, including the 5592 Å CE line, have been measured and their ratios compared with models.
In the title compound, C21H17N2P, the dihedral angles between the 1,5-naphthyridine ring system (r.m.s. deviation = 0.005 Å) and the phenyl rings are 89.18 (8) and 77.39 (8)°. The phenyl rings are almost perpendicular, making a dihedral angle of 88.12 (8)°. The only possible inter-molecular inter-action is a very weak aromatic π-π stacking inter-action [centroid-centroid separation = 3.898 (2) Å].
Blind methods are powerful tools when very weak information is necessary. Although many algorithms can be called blind, in this paper, we focus on blind source separation (BSS) and independent component analysis (ICA). After a discussion concerning the blind nature of these techniques, we review three main points: the separability, the criteria, the algorithms.
The title Schiff base, C18H15NO, crystallizes in its zwitterionic form and an N-H⋯O hydrogen bond closes an S(6) ring. The dihedral angle between the aromatic ring systems is 36.91 (10)°. Weak aromatic π-π stacking occurs in the crystal [minimum centroid-centroid separation = 3.7771 (15) Å].
In the title compound, C(22)H(23)NO(4)S(2), the dihedral angles between the dimethyl-phenyl ring and the two methyl-phenyl rings are 41.19 (15) and 20.50 (17)°; the dihedral angle between the methyl-phenyl rings is 48.11 (14)°. The C-N-S-C torsion angles are -87.6 (2) and 77.43 (18)°. The only possible directional inter-actions in the crystal are very weak C-H⋯π inter-actions and very weak π-π ...
In the title compound, C(8)H(6)N(2)O(2), inter-molecular N-H⋯O hydrogen bonds involving the amine and carbonyl groups create centrosymmetric dimers between adjacent nearly coplanar mol-ecules. These dimers are further connected by weak N-H⋯O hydrogen bonds, forming a two-dimensional network. Mol-ecules are packed in the crystal structure with adjacent benzene and pyrimidine rings approximately ...
In the title compound, C(20)H(14)ClP, the dihedral angle between the naphthyl rings is 81.77 (6)°. The crystal packing suggests weak π-π stacking inter-actions between the naphthyl rings in adjacent units [minimum ring centroid separation 3.7625 (13) Å].
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