The neutron scattering studies of the sublattice magnetization in the vicinity of the N&l temperature in 7 Mno.6Feo.37Cuo.03 alloy reveal its marked critical behaviour. The staggered transverse susceptibility and correlation length remain finite at TN and some anisotropic features of critical scattering are observed. Although the critical magnetic scattering in y-Mn alloys was studied for the f...

Complex assembly preferences and resultant spin state choice Jahn-Teller distortion mode in twelve Mn(III) complexes of varying nuclearity with Schiff base chelate ligands different sizes are compared. Mononuclear Mn(5-F-Sal2323)]OTf (1), [Mn(5-F-Sal2323)]ClO4 (2) [Mn(5-F-Sal2323)]NO3, (3) the 8-carbon R-Sal2323 type show rare axial compression at room temperature also reversible thermal switch...

A novel S4-symmetric icosanuclear manganese metalladiazamacrocycle was synthesized using a pentadentate ligand, N-3-phenyl-trans-2-propenoylsalicylhydrazide (H3L), that has a rigid and bulky terminal N-acyl group. A 20 cyclic repeat of an--(Mn-N-N)--linkage resulted in a highly puckered diaza-bridged 60-membered icosanuclear metallamacrocycle. The steric interaction between the ligands in the c...

The aim of the present work was to investigate the processes involved in the origin of trisomic karyotypes, i.e. co-migration of sister chromatids (mitotic non-disjunction, MND) and recovery of micronuclei (MN) originating from lagging chromosomes/chromatids at anaphase (mitotic indirect non-disjunction, MIND), and to evaluate their relative contribution to aneuploidy in human lymphocytes mitot...

Biogenic manganese oxides (BioMnOx) were synthesized by the oxidation of Mn(II) with Mn-oxidizing bacteria Pseudomonas sp. G7 under different initial pH values and Mn(II) dosages, and were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and UV-Vis absorption spectroscopy. The crystal structure and Mn oxidation states of BioMnOx depended on the initial pH and Mn(II) dosages...

220. Ongoing Impact of an Antimicrobial Stewardship Program at A Large Academic Medical Center, 7 years of experience Susan Kline, MD, MPH; Kimberly Boeser, PharmD, BCPS AQ-ID; Teresa Rakoczy, RN, BSN; Amanda Guspiel, MPH; Anita Guelcher, RN, BSN; Christine Hendrickson, RN, BSN; Pamela Phelps, PharmD; Medicine/Infectious Diseases, University of Minnesota Medical School and University of MN Medi...

The precise analysis of redox chemistry of MN4-based macrocyclic complexes is of great importance because of stabilization of unusual oxidation states of metal ions by macrocyclic ligand and thus have various applications in biochemistry, electrochemistry, electrocatalysis, pharmaceuticals etc. In this work, MN4-macrocyclic complexes of Co (II) and Ni(II) transition metal ...