نتایج جستجو برای: acidity constant

تعداد نتایج: 227783  

2013
Isabella Poggi Francesca D'Errico

The paper overviews previous works on acidity and acid communication, their nature and causes. Then it presents a qualitative study on a real case of acid communication in an Italian politician. An annotation scheme is proposed to single out ingredients of multimodal acid communication, and the mental ingredients of annoyance, distance, defiance are found as characterizing acidity.

Journal: :Physical chemistry chemical physics : PCCP 2015
Weihong Wu Yunxiang Lu Hairong Ding Changjun Peng Honglai Liu

Metal-containing ionic liquids (ILs) have been recognized as potential solvents, catalysts, catalyst precursors and reagents for many organic processes. In this work, several quantum-chemical parameters, including the surface electrostatic potential (Vs,max and Vs,min), the lowest surface average local ionization energy (I̅s,min), and the electrostatic potential at the position of an atom (EPnuc...

Journal: :European journal of endocrinology 1998
U Plöckinger A Perez-Canto C Emde R M Liehr W Hopfenmüller H J Quabbe

OBJECTIVE To study the effects of the somatostatin analog octreotide on gastric mucosal function and histology during short-term (3 months) preoperative treatment in patients with acromegaly. DESIGN Open design clinical study. METHODS 10 patients were studied before treatment with octreotide (pre-tx), on day 1 of 300 microg octreotide/day (d300), after 1 week on 300 (w300), 600 (w600) or 15...

Journal: :journal of physical & theoretical chemistry 2005
farrokh gharib

the formation constants of the species formed in the systems fr + glycine + dioxovanadium(v) + and h+ + glycine have been determined in aqueous solutions of methanol at 25 °c and constant ionicstrength, using spectrophotometric and potentiometric techniques. it was shown thatdioxovanadium(v) forms two mononuclear 1 : land 1:2 complexes with glycine. the formationconstants in various media were ...

Journal: :Journal of research in health sciences 2009
Sh Dolatshahi M Malakootian H Akbari

BACKGROUND High consumption of nonalcoholic beverages is one of the causes of dental erosion. Annual consumption of beverages in Iran is 48 LPCY (Lit per capita per year) that is equal to 144 bottles per capita in year and is relatively a high rate. Taking this into consideration, the present study was planned to determine the pH and fluoride content of beverages consumed in Kerman, south east ...

Journal: :ACS chemical biology 2013
Aaron Bender Zachary R Woydziak Liqiang Fu Michael Branden Zhenguo Zhou Brian D Ackley Blake R Peterson

Unlike the digestive systems of vertebrate animals, the lumen of the alimentary canal of Caenorhabditis elegans is unsegmented and weakly acidic (pH ~4.4), with ultradian fluctuations to pH > 6 every 45-50 s. To probe the dynamics of this acidity, we synthesized novel acid-activated fluorophores termed Kansas Reds. These dicationic derivatives of rhodamine B become concentrated in the lumen of ...

2017
Lingqian Meng Xiaochun Zhu Brahim Mezari Robert Pestman Wannaruedee Wannapakdee Emiel J M Hensen

The influence of framework substituents (Al3+, Ga3+, Fe3+ and B3+) and morphology (bulk vs. nanometer-sized sheets) of MFI zeolites on the acidity and catalytic performance in the methanol-to-hydrocarbons (MTH) reaction was investigated. The Brønsted acid density and strength decreased in the order Al(OH)Si>Ga(OH)Si>Fe(OH)Si≫B(OH)Si. Pyridine 15N NMR spectra confirmed the differences in the Brø...

Journal: :The journal of physical chemistry. B 2013
Shashi Kant Shukla Anil Kumar

Acidity functions were used to express the ability of a solvent/solution to donate/accept a proton to a solute. The present work accounts for the acidity determination of HCOOH, CH3COOH, and CH3CH2COOH in the alkylimidazolium-based protic ionic liquids (PILs), incorporated with carboxylate anion, water, and in a binary mixture of PIL and water using the Hammett acidity function, H0. A reversal ...

Journal: :Dalton transactions 2015
Ana Martín-Sómer Otilia Mó Manuel Yáñez Jean-Claude Guillemin

The intrinsic acidity of CH2[double bond, length as m-dash]CHXH2, HC[triple bond, length as m-dash]CXH2 (X = N, P, As, Sb) derivatives and of their complexes with BeH2 and BH3 has been investigated by means of high-level density functional theory and molecular orbital ab initio calculations, using as a reference the ethyl saturated analogues. The acidity of the free systems steadily increases d...

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