Flash photolysis of 10-diazo-9(10H)-phenanthrenone in aqueous solution was found to give two successively formed transient species and to produce fluorene-9-carboxylic acid as the major reaction product. These transients were identified, through solvent isotope effects and the form of acid-base catalysis, as fluorenylideneketene, formed by photo-Wolff reaction of the diazophenanthrenone, and fl...

Cross-metathesis involving N-heteroaromatic olefinic derivatives is disclosed. The introduction of an appropriate substituent on the heteroaromatic ring decreases the Lewis basicity of the nitrogen atom, thus preventing the deactivation of the ruthenium-centered catalyst. The reaction is quite general in terms of both N-heterocycles and olefinic partners.

The N-heterocyclic olefin, IPr=CH(2) (IPr = [(HCNDipp)(2)C], Dipp = 2,6-(i)Pr(2)C(6)H(3)) has been demonstrated to be of sufficient Lewis basicity to stabilize main group hydrides in unusually low oxidation states.

BACKGROUND Faba bean is an important starch-based protein crop produced worldwide. Soil acidity and aluminium toxicity are major abiotic stresses affecting its production, so in regions where soil acidity is a problem, there is a gap between the potential and actual productivity of the crop. Hence, we set out to evaluate acidity and aluminium tolerance in a range of faba bean germplasm using so...

We consider a perturbed system of exponents { en } n∈Z, when the sequence {λn }n∈Z has a definite asymptotics. We study basis properties (completeness, minimality, basicity) of this system in Lebesgue space of functions Lp(·) (−π, π) with variable summability exponent p(·), subject to parameters contained in the asymptotics {λn}n∈Z.

The very large cells of the marine green alga Valonia macrophysa permit one to obtain several cubic centimeters of fluid from the central vacuole of a single cell (cf. Wodehouse, 1917), without involving appreciable alteration in the composition of the cell-sap through protoplasmic 'injury during the process of extraction (cf. Chambers, 1917). Estimations have been made of the acidity of this c...