Two isoreticular series of pyrazolate-based 3D open metal-organic frameworks, MBDP_X, adopting the NiBDP and ZnBDP structure types [H(2)BDP = 1,4-bis(1H-pyrazol-4-yl)benzene], were synthesized with the new tagged organic linkers H(2)BDP_X (X = -NO(2), -NH(2), -OH). All of the MBDP_X materials have been characterized through a combination of techniques. IR spectroscopy proved the effective prese...

The work described in this thesis concerns the plasma polymers used for immobilization and adsorption of biomolecules. In particular, thin polymeric films bearing ether, anhydride, and amine functionalities were synthesis by plasma polymerization of these group containing monomers, i.e. di-(ethylene glycol) vinyl ether (EO2), maleic anhydride (MA), and allylamine (AA). Additionally, the charact...

the work focuses on the removing of cu(ii) from aqueous solution by linde f(k) zeolite. the zeolite is synthesized from fly ash by hydrothermal process. the adsorption experiments discuss several factors including the optimal solution ph, zeolite dosage, adsorption temperature, adsorption kinetics and adsorption isotherm equation. the results show that, the optimal solution ph is 6 and the effi...

Here we present a systematic study of the adsorption and laser induced desorption of CO, NO and CO + NO from a Pd(111) surface at a number of different coverages. We begin by characterising the surfaces using reflection-absorption infrared spectroscopy (RAIRS) and temperatureprogrammed desorption (TPD). Experiments show that NO displaces pre-adsorbed CO considerably, but that CO has a much smal...

The hydrogen evolution reaction (HER) on Ni in alkaline media was investigated by scanning electrochemical microscopy under two operating modes. First, the substrate generation/tip collection mode was employed to extract the "true" cathodic current associated with the HER from the total current in the polarization curve. Compared to metallic Ni, the electrocatalytic activity of the HER is impro...

The electrochemical behaviour of hen-egg-white lysozyme (HEWL) was studied at the polarized water/1,2-dichloroethane interface. The voltammetric ion-transfer response was found to be dependent on the pH and ionic strength of the aqueous phase solution and also on the nature of the organic phase electrolyte anion. The current-pH behaviour of HEWL was dominated by the charge of the biomolecule at...

A new visual colorimetry for trace antimony(V) based on ion-pair solid-phase extraction to a PTFE-type membrane filter with bis[2-(5-chloro-2-pyridylazo)-5-diethylaminophenolato]cobalt(III) ion ([Co(5-Cl-PADAP)(2)](+)) has been developed. Experiments showed that hexachloroantimonate(V) ion (SbCl(6)(-)) was adsorbed with [Co(5-Cl-PADAP)(2)](+) to the front surface of the PTFE filter. The adsorpt...

Antifreeze proteins (AFPs) and antifreeze glycoproteins (AFGPs), collectively abbreviated as AF(G)Ps, are synthesized by various organisms to enable their cells to survive in subzero environments. Although the AF(G)Ps are markedly diverse in structure, they all function by adsorbing to the surface of embryonic ice crystals to inhibit their growth. This adsorption results in a freezing temperatu...

We present first-principles calculations of the sticking coefficient of O2 at Pd(100) to assess the effect of phononic energy dissipation on this kinetic parameter. For this, we augment dynamical simulations on six-dimensional potential energy surfaces (PESs) representing the molecular degrees of freedom with various effective accounts of surface mobility. In comparison to the prevalent frozen-...

Nitrogen adsorption experiments have been extensively applied to shale pore structure research and evaluation. The can be quantitatively characterized in accordance with the nitrogen adsorption–desorption isotherm using various calculation models, whereas results obtained different models more effectively indicate characteristics of remains unclear. Further, there has not any unified process op...