نتایج جستجو برای: aldol reaction

تعداد نتایج: 413188  

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه پیام نور - دانشگاه پیام نور استان زنجان - دانشگاه پیام نور مرکز ابهر - دانشکده علوم پایه 1388

چکیده ندارد.

The aim of this study was to synthesize a new oxetan-phenyltetrahydropyridazine-3,6-dione derivative (compound 6) using with different techniques. The first method was achieved by the preparation of a phenylhydrazine derivative (2) using three components system (3,17-aldol-estradiol, phenylhydrazine, 5-hexyn-3-ol) in presence of Copper(II). Then, 2 Was reacted with tert-butyldimethylsilyl chlor...

Journal: :Journal of the American Chemical Society 2003
David A Evans Bernard Côté Paul J Coleman Brian T Connell

This article presents studies that illustrate beta-alkoxy methyl ketone-derived boron enolates undergo diastereoselective aldol addition to afford the 1,5-anti diol relationship. The stereochemical outcome of this reaction is documented to be general for a variety of beta-alkoxy methyl ketone analogues and aldehyde partners. The double stereodifferentiating reactions of these enolates with chir...

Journal: :Journal of molecular biology 2004
Xueyong Zhu Fujie Tanaka Yunfeng Hu Andreas Heine Roberta Fuller Guofu Zhong Arthur J Olson Richard A Lerner Carlos F Barbas Ian A Wilson

Catalytic aldolase antibodies, generated by reactive immunization, catalyze the aldol reaction with the efficiency of natural enzymes, but accept a much broader range of substrates. Two separate groups of aldolase antibodies that catalyze the same aldol reactions with antipodal selectivity were analyzed by comparing their amino acid sequences with their crystal structures, site-directed mutagen...

Journal: :Organic & biomolecular chemistry 2012
Jinqing Zhou Jinwei Wan Xuebing Ma Wei Wang

In the current study, a convenient and simple way is presented to synthesize a novel type of supported heterogeneous organocatalyst in 21-81% yield by the copolymerization of 9-amino-9-deoxy-epi-cinchonine organocatalyst with acrylonitrile using AIBN as radical initiator. The chemical compositions (x/y) and weight-average molecular weights of copolymers 1a-d were determined by (1)H NMR and GPC ...

Journal: :Angewandte Chemie International Edition 2007

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