When perovskite-structured BaCe03 is doped with M ~ + ions (e.g., ~ d ~ + , Gd3+,yb33 that substitute on ce4+ sites, oxygen-ion vacancies are created for charge compensation. However, when treated in water vapor, the vacancies are replaced by protons, which take the form of OH' ions. This treatment makes the materials a good protonic conductor. Questions about the defect structure of the proton...