In this work some organic natural products were studied, namely tannic acid, gallic mimosa tannin and chestnut tannin, as potential green corrosion inhibitors of the aluminium alloy AA2024-T3. The anodizing treatment was performed in a solution referred compounds diluted sulfuric acid. electrochemical impedance spectroscopy potentiodynamic polarization to assess sealing quality protection grant...

The kinetics of anodic oxidation of zircaloy-2, zircaloy-4, titanium and niobium have been studied in 0.1M sodium methoxide without and with addition of a millimole of sodium phosphate at a constant current density of 8mA.cm-2 and at room temperature (300 K). the addition of phosphate ions found to improve the kinetics of film formation. This trend and mechanism of anodic oxide film growth is c...

A series ef binary Ti-Cu alloys containing 5-20 mass% Cu was prepared, and the corresien behavior of a-Ti and Ti2Cu composing the Ti-Cu alloys were examined based on the anodic polarization curves and released iens in O.9% NaCl and 1% lactic acid solutions. In both selutions, the Ti-Cu alloys showed the same anodic polarization curves as titanium in the conditien below 1.4 V. Hewever, precipita...

An anodic cyclization-Friedel Crafts alkylation strategy has been used to rapidly assemble the core ring system of alliacol A and to complete a formal total synthesis of the natural product. The anodic cyclization reaction was used to effect the coupling of a nucleophilic furan ring to the normally nucleophilic carbon of a silyl enol ether. The substrate for this initial cyclization reaction co...

The electrochemical behavior of thiamine on a self-assembled electrode of L-cysteine (Cys/SAM/Au) has been investigated and Cys/SAM/Au can be used to detect thiamine using square-wave voltammetry (SWV). At pH 11.40 Britton-Robinson buffer, thiamine exhibits a well-defined anodic peak on Cys/SAM/Au. Under the optimized conditions, the anodic peak current of SWV was linear with the content of thi...

The electrochemical behavior of copper in 0.05 M HCl and 0.05 M NaCl carried out at open-circuit potential and at constant anodic potential after one hour has been investigated using electrochemical impedance spectroscopy (EIS) at 20 °C, 40 °C and 60 °C. The formation of copper chloride (CuCl) film does not protect copper from dissolution in the chloride media. The physical properties of the pa...

A detailed study of the pore-widening rate of nanoporous anodic alumina layers as a function of the anodization voltage was carried out. The study focuses on samples produced under the same electrolyte and concentration but different anodization voltages within the self-ordering regime. By means of ellipsometry-based optical characterization, it is shown that in the pore-widening process, the p...

A nanostructure composed of Anodic Aluminum Oxide (AAO) was obtained on an electrode of a quartz crystal microbalance (QCM) chip by anodizing Al thin film in an oxalic acid solution. The effective surface area was expanded by these nanostructures. Several morphologies were observed under various anodic conditions by using scanning electron microscopy (SEM). We demonstrated that a QCM chip with ...

Abstract The resilience of mild steel to electrochemical degeneration in weak electrolyte corrosion (0.5 M HCl) was assessed at discrete concentrations Norcholine derivatives by potentiodynamic polarization and open circuit potential analysis. Degradation rate the substantially declined with augmentation concentration from 9.49 mm/y control HCl (no Norcholine) 0.27 highest value 15%. degradatio...