Solvent effects on 2,6-dichloro-4-(2,4,6-triphenyl-pyridinium-1-yl)phenolate [ET (33) dye] and 7diethylamino-3,4-benzophenoxazine-2-one (Nile Red) in binary mixtures of organic solvents (acetone, acetonitrile, propylene carbonate, methanol and ethane-1,2-diol) with 1,3-dialkyl imidazoliumbased ionic liquids were studied by UV-visible spectroscopy. Highly nonlinear behaviour of mixtures of alcoh...

We have developed a framework of the thermodynamics and hydrodynamics of chemically crosslinked gels in a binary miscible solvent. This work is an extension of a previous one on gels in a single solvent [Sekimoto K., J. Phys. II France1 (1991) 19]. Introduction of a composition degree of freedom of the solvent leads to both thermodynamic chemo-mechanical coupling and kinematical cros~coupling b...

NAD(P)-dependent oxidoreductases are valuable tools for the synthesis of chiral compounds. Due to the high cost of the pyridine cofactors, in situ cofactor regeneration is required for preparative applications. In recent years, existing regeneration methodologies have been improved and new approaches have been devised. These include the use of newly discovered dehydrogenases that are stable in ...

The solubility of polymers can be significantly altered by the use of solvent mixtures. The solvent composition also effects the self-assembly properties of amphiphilic copolymers. In addition, water–ethanol mixtures are known to exhibit abnormal physicochemical properties due to the presence of hydration shells around the ethanol molecules, while at the same time both solvents have very low to...

The conductance o f N al in acetonitrile-water mixtures was measured at 25.000 ± 0.001 °C for the whole com position range o f the mixed solvent, the salt molarity ranging from 5 • 10“ 5 to 1 • 10-2 . Using the Fuoss-Hsia equation with the Femandez-Prini parameters, the association constants were computed for several values o f the ion-ion distances. The influence o f the mixed solvent composit...

We use mixed quantum-classical molecular dynamics simulations and ultrafast transient hole-burning spectroscopy to build a molecular-level picture of the motions of solvent molecules around Na atoms in liquid tetrahydrofuran. We find that even at room temperature, the solvation of Na atoms occurs in discrete steps, with the number of solvent molecules nearest the atom changing one at a time. Th...

The group separation of trivalent actinides and lanthanides and the mutual separation of americium and curium are necessary for the transmutation of americium. We have proposed the separation system based on the chromatography using the tertiary pyridine-type resin. In this separation system, the complete separation method of the trivalent actinides and lanthanides are already established using...

Computational chemistry has recently introduced the improved reaction field theory and now is capable of evaluating the bulk solvent effect quite accurately. It is time to expand this capability to mixed solvents, as it is often extremely useful through is still not well understood. For example, the determination of rates of complexations of divalent metal ions with a tridentate metal-ion indic...

This article discusses recent progress by a combination of spectroscopy and quantum-chemical calculations in classifying and characterizing organic mixed-valence systems in terms of their localized vs. delocalized character. A recently developed quantum-chemical protocol based on non-standard hybrid functionals and continuum solvent models is evaluated for an extended set of mixed-valence bis-t...