Abstract Surfactant‐free one‐step redox reactions between two types of metal cations enable the synthesis core‐shell nanoparticles without sophisticated control. The reduced noble form a solid core, and transition dissolved upon oxidation induce subsequent formation oxide shell. Various nanostructures are obtained from combination reduction‐preferring Au 3+ , Pd 2+ Pt Rh Ir cations, oxidation‐p...