We have demonstrated an improved synthesis of a cyclic carbonate of soybean oil (CSO) utilizing supercritical carbon dioxide (CO2) as the solvent. Because the mutual solubility of supercritical CO2 and soybean oil is significantly higher than that of gaseous CO2 and soybean oil, our method synthesizes the material in y1/3 of the reaction time reported in the literature. We have also demonstrate...

A stable magnetic nanocomposite of collagen and superparamagnetic iron oxide nanoparticles (SPIONs) is prepared by a simple process utilizing protein wastes from leather industry. Molecular interaction between helical collagen fibers and spherical SPIONs is proven through calorimetric, microscopic and spectroscopic techniques. This nanocomposite exhibited selective oil absorption and magnetic t...

Bio-oil is a blackish liquid fuel derived from biomass such as corn cobs, rice husks and other cocoa shells. The organic acid content in bio-oil gives acidic properties. can be obtained the pyrolysis combustion process, using tube. number of tubes used affect yield characteristics bio-oil. purpose this study was to determine produced by varying process. Such time, amount bio-oil, temperature Th...

INTRODUCTION The environmental concerns, including dwindling crude oil resources, high oil prices, pollution, greenhouse CO2 emissions, and toxicity in the environment, married to societal pressures towards sustainable development are currently making countries around the world turn to biomass as a renewable resource for a variety of products: fuels, lubricants, chemicals, polymers, fibers, neu...

To address the issues of greenhouse gas emissions associated with fossil fuels, vegetable oilseeds, especially non-food oilseeds, are used as an alternative fuel resource. Vegetable oil derived from these oilseeds can be upgraded into hydrocarbon biofuel. Catalytic cracking and hydroprocessing are two of the most promising pathways for converting vegetable oil to hydrocarbon biofuel. Heterogene...

The article presents the experimental data on the extraction and transesterification of bio-oil derived from Stoechospermum marginatum, a brown macro marine algae. The samples were collected from Mandapam region, Gulf of Mannar, Tamil Nadu, India. The bio-oil was extracted using Soxhlet technique with a lipid extraction efficiency of 24.4%. Single stage transesterification was adopted due to lo...

This paper evaluates the economic feasibility of an integrated production pathway combining fast pyrolysis and bio-oil gasification. The conversion process is simulated with Aspen Plus® for a 2000 metric ton per day facility. Techno-economic analysis of this integrated pathway has been conducted. A total capital investment of $510 million has been estimated and the minimum fuel selling price (M...

Aqueous-phase reforming (APR) of the low-boiling fraction (LBF) of bio-oil from rice husk pyrolysis was investigated over Pt/Al(2)O(3) for hydrogen production. The influence of reaction temperature (503-563 K), reaction time (1-4h), different load of organics in water (3-12 wt.%) and catalyst amounts (0.25-1g) were studied. The hydrogen content of the gas products reached 65 vol.% at 533 K for ...

The present study was designed to evaluate the performance of alternative bio-based solvents, more especially 2-methyltetrahydrofuran, obtained from crop's byproducts for the substitution of petroleum solvents such as hexane in the extraction of fat and oils for food (edible oil) and non-food (bio fuel) applications. First a solvent selection as well as an evaluation of the performance was made...

The pyrolysis behavior and kinetics of the aqueous fraction of bio-oil were studied through thermogravimetric (TG) analysis. Based on the experimental data, activation energies and kinetic parameters were calculated by the Achar differential method and the Coats-Redfern integral method, then the most probable mechanism functions and kinetics model were obtained at last. The results show that th...