In the formulation of zeolite-based catalysts for direct cracking crude, use kaolin matrixes prevents, to a large extent, zeolite dealumination. Metals and other impurities in crude oil provoke slight decrease activity selectivity patterns.

We decorated HS-functionalized cellulose nanocrystallite (CNC) films with monodisperse Au nanoparticles (AuNPs) to form a novel nanocomposite catalyst AuNPs@HS-CNC. The uniform, fine AuNPs were made by the reduction of HAuCl4 solution with thiol (HS-) group-functionalized CNC films. The AuNPs@HS-CNC nanocomposites were examined by X-ray photoelectron spectroscopy (XPS), TEM, ATR-IR and solid-st...

The performance of Fe/olivine catalysts was tested in the continuous steam gasification sawdust a bench scale plant provided with fountain confined conical spouted bed reactor at 850 °C. Olivine used as catalyst support and loaded 5 wt%Fe. activity stability monitored by nitrogen adsorption-desorption, X-ray fluorescence spectroscopy, temperature programmed reduction, diffraction photoelectron ...

High-throughput development of catalysts, initiators, and polymeric materials combines automated parallel catalyst synthesis and automated polymerization reactors. The reactors can be additionally equipped with on-line monitoring (ReactIR from Mettler) based on ATR-FT-IR technique. This powerful tool has proven to be a very valuable probe for high-throughput experiments. During copolymerization...

The presence of biogenic or process-derived impurities poses a major problem on the efficient catalytic hydrogenation of biomass-derived levulinic acid to γ-valerolactone; hence, studies on their influence on catalyst stability are now required. Herein, the influence of sulfuric acid as feed impurity on the performance of Ru-based heterogeneous catalysts, including Ru/ZrO2 and mono- and bimetal...

The widespread use of fuel cells is currently limited by the lack of efficient and cost-effective catalysts for the oxygen reduction reaction. Iron-based non-precious metal catalysts exhibit promising activity and stability, as an alternative to state-of-the-art platinum catalysts. However, the identity of the active species in non-precious metal catalysts remains elusive, impeding the developm...

Since the introduction in I974 of catalytic converters for automotive emission control i n the United States significant advances have been made in the design of durable monolith supported catalysts for the control of carbon monoxide, unburnt hydrocarbon and nitrogen oxide emissions. However, high temperature durability, has been a significant problem, particularly of three-way catalysts. Johns...

The insertion of internal olefins (hydroalumination) and chain walking isomerisation at di-n-octylaluminium hydride [Al(Oct)2H], promoted by zirconocene dichloride [Cp2ZrCl2] has been studied. The reaction between [Cp2ZrCl2] and [Al(Oct)2H] in non-polar solvents leads to clusters containing bridging hydride ligands between Zr and Al. This system promotes hydroalumination of 1-octene but is larg...

Optimized growth of single wall carbon nanotubes requires full knowledge of the actual state of the catalyst nanoparticle and its interface with the tube. Using tight binding based atomistic computer simulations, we calculate carbon adsorption isotherms on nanoparticles of nickel, a typical catalyst, and show that carbon solubility increases for smaller nanoparticles that are either molten or s...

The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of benzyl alcohol, which has been studied by gas-uptake kinetic methods and (1)H NMR spectroscopy. The data reveal that turnover-limiting substrate oxida...