Charge transfer in DNA cannot be understood without addressing the complex conformational flexibility, which occurs on a wide range of timescales. In order to reduce this complexity four dinucleotide models 1X consisting of benzophenone linked by a phosphodiester to one of the natural nucleosides X = A, G, T, C were studied in water and methanol. The theoretical work focuses on the dynamics and...

electrochemical impedance spectroscopy (eis) is a suitable and powerful diagnostic testing method for fuel cells (fcs) since it is non-destructive and provides useful information about fc performance and its components. in this study, for the first time, a 500w cascade type 4 cells stack with integrated humidifier, water separator and internal manifolds was designed, fabricated and tested. the ...

The photophysical properties of 6-phenyl-2,2'-bipyridyl platinum(ii) complexes bearing different σ-alkynyl-linked azobenzene ancillary ligands were investigated. These complexes exhibited strong, broad, structureless charge-transfer bands in the visible region, which were red-shifted when the electron-donating ability of the para substituent on the azo-acetylide ligand increased. When excited a...

A zero-crossing based pipelined analog-to-digital converter (ADC) has been designed and is fabricated in a 65nm CMOS process. The highly digital implementation characteristic of the zero-crossing detection technique enables energy efficient operation and voltage scaling. Supply voltage scaling based on the required sampling frequency and resolution provides high energy efficiency over a wide ra...

Charge transfer in DNA cannot be understood without addressing the complex conformational flexibility, which occurs on a wide range of timescales. In order to reduce this complexity four dinucleotide models 1X consisting of benzophenone linked by a phosphodiester to one of the natural nucleosides X = A, G, T, C were studied in water and methanol. The theoretical work focuses on the dynamics and...

After a most refreshing discussion of the generation of energy through ATP and the oxidative cycle, the author outlines the methods of quantitating electron donor or electron acceptor molecules. He briefly considers the biological role of electromagnetic coupling and semiconduction in electronic mobility. However, he deals more extensively with charge transfer which "may be one of the most impo...

Understanding the mechanism of singlet exciton fission, in which a singlet exciton separates into a pair of triplet excitons, is crucial to the development of new chromophores for efficient fission-sensitized solar cells. The challenge of controlling molecular packing and energy levels in the solid state precludes clear determination of the singlet fission pathway. Here, we circumvent this diff...

Determining covalent and charge-transfer contributions to bonding in solution has remained an experimental challenge. Here, the quenching of fluorescence decay channels as expressed in dips in the L-edge X-ray spectra of solvated 3d transition-metal ions and complexes was reported as a probe. With a full set of experimental and theoretical ab initio L-edge X-ray spectra of aqueous Cr(3+), inclu...

Understanding the role of intermolecular interaction on through-space charge transfer characteristics in π-stacked molecular systems is central to the rational design of electronic materials. However, a quantitative study of charge transfer in such systems is often difficult because of poor control over molecular morphology. Here we use the core-hole clock implementation of resonant photoemissi...

Charge transfer and fragmentation in collisions of sodium cluster ions with caesium atoms have been investigated theoretically within a microscopic framework called Non-adiabatic Quantum Molecular Dynamics. To illustrate the complexity of non-adiabatic cluster collisions, in particular the interplay between charge transfer and fragmentation, Na4 (2.7 keV) + Cs collisions are studied in detail w...