We report on phase sensitive surface states of CdS quantum dots (QDs), where it is noticed that a simple phase change from dispersion to solid has shown significant influence on the emission spectrum. As the solvent evaporates from the dispersion, apparently yellow dispersion transforms into a white light emitter because of the conformal changes in the polymer that surrounds the QDs. In turn, t...

OBJECTIVE In our previous study, we reported a novel approach of delivering liposomes in dry powder form that relies on spontaneous formation of liposomes upon dispersion of micronised phospholipid(s) based powders in an aqueous environment, thereby creating reservoirs for the encapsulation of drugs [J. Pharm. Sci. 91 (2002) 482]. In this paper, we demonstrate the in vitro generation of aerosol...

Weak, intermolecular interactions in amine dimers were studied by using the combination of a dispersionless density functional and a function that describes the dispersion contribution to the interaction energy. The validity of this method was shown by comparison of structural and energetic properties with data obtained with a conventional density functional and the coupled cluster method. The ...

The differential migration of ions in an applied electric field is the basis for separation of chemical species by capillary electrophoresis. Axial diffusion of the concentration peak limits the separation efficiency. Electromigration dispersion is observed when the concentration of sample ions is comparable to that of the background ions. Under such conditions, the local electrical conductivit...

Supramolecular host-guest systems play an important role for a wide range of applications in chemistry and biology. The prediction of the stability of host-guest complexes represents a great challenge to first-principles calculations due to an interplay of a wide variety of covalent and noncovalent interactions in these systems. In particular, van der Waals (vdW) dispersion interactions frequen...

A derivation of the Dirac equation in ‘3 + 1’ dimensions is presented based on a master equation approach originally developed for the ‘1+ 1’ problem by McKeon and Ord. The method of derivation presented here suggests a mechanism by which the work of Knuth and Bahrenyi on causal sets may be extended to a derivation of the Dirac equation in the context of an inference problem.

Measurements in atmospheric science sometimes determine universal functions, but more commonly data are collected in the form of case studies. Models are conceptual constructs that can be used to make predictions about the outcomes of measurements. Hypotheses can be expressed in terms of model results, and the best use of measurements is to falsify such hypotheses. Tuning of models should be av...

The synthesis of carbon nanotubes (CNTs) by chemical vapor deposition (CVD) of isobutane (i‐C4H10) over sodium‐exchanged K10‐montmorillonite based iron‐ catalysts is investigated. By studying the influence of iron‐addition (5–25 wt%) on the catalyst performances, at 700 °C, an empirical relationship is derived relating the mass of CNTs synthesized with the exposed ...

CFD Modelling of Nanoparticles Dispersion in a Dust Explosion Apparatus Carlos Murillo, Olivier Dufaud, Omar López, Laurent Perrin, Alexis Vignes, Felipe Muñoz. Chemical Engineering Department, Universidad de los Andes, Colombia. Laboratoire des Sciences du Génie Chimique (LSGC), Nancy-Université, CNRS 1, rue Grandville, BP 20451, 54001 Nancy, France. Mechanical Engineering Department, Universi...