The kinetics of reduction and oxidation of soluble chromium in various soils (peat, clay, sand, and luvi-chromic cambisols) were studied at constant soil moisture and constant temperature. A total of 1500 g of each soil was incubated with different concentrations of aqueous solutions of K2Cr2O7 or CrCl3 [1-1000 μg (g of dry soil)-1]. The total exchangeable chromium and Cr(VI) were analyzed in s...

Background The objective of this study is to suggest revised recognition standards for occupational disease due to chromium (VI) by reflecting recent domestic and international research works and considering domestic exposure status with respect to target organs, exposure period, and cumulative exposure dose in relation to the chromium (VI)-induced occupational disease compensation. Methods I...

Nine bacterial colonies were screened for the Cr(VI) removal efficiency and out of these three bacterial strains Pseudomonas putida, Pseudomonas aeruginosa and Bacillus sp. were isolated from soil and used to remove Cr(VI) from aqueous solution. The effect of time and concentrations on the removal rate of hexavalent chromium were studied using batch experiment. Maximum Cr (VI) removal was noted...

presence of heavy metals in the aquatic systems has become a serious problem. as a result, therehas been a great deal of attention given to new technologies for removal of heavy metal ions from contaminated waters. adsorption is one of the effective methods for removal of toxic heavy metal such as chromium (vi). in the present study, adsorbent is prepared from rice husk, a low cost by product f...

presence of heavy metals in the aquatic systems has become a serious problem. as a result, therehas been a great deal of attention given to new technologies for removal of heavy metal ions from contaminated waters. adsorption is one of the effective methods for removal of toxic heavy metal such as chromium (vi). in the present study, adsorbent is prepared from rice husk, a low cost by product f...

A new time-based flow injection on-line solid phase extraction method for chromium(VI) and lead determination using flame atomic absorption spectrometry was developed. The use of hydrophobic poly-chlorotrifluoroethylene (PCTFE)-beads as absorbent in on-line preconcentration system was evaluated. Effective formation of ammonium pyrrolidine dithiocarbamate complexes and subsequently retention in ...

Reaction of chromium(VI) with one equivalent of ascorbate was studied by electron paramagnetic resonance spectroscopy in the presence of 0.10 M 5,5-dimethyl-1-pyrroline-1-oxide (DMPO) at room temperature in 0.10 M (N-[2-hydroxyethyl]piperazine-N'-[2-ethanesulfonic acid]) (HEPES) and 0.05 M tris(hydroxymethyl)aminomethane hydrochloride (Tris-HCl) buffers (pH 7.0 room temperature). Chromium(V), a...

Heavy metals have significant importance in altering the immune response. Chromium is found in the environment commonly in trivalent, Cr (III), and hexavalent, Cr (VI), forms. The reduction of Cr (VI) to Cr (III) results in the formation of reactive intermediates (ROS) that contribute to the cytotoxicity and genotoxicity. In this study mice were treated with chromium (VI) oxide (24 mg /kg body ...

abstract background: heavy metals in industrial wastewater especially chromium (vi) are considered as the main environmental pollutants. methods: electrochemical cell made of plexiglass with a volume of 1.95 lit was used. iron and graphite electrodes, electricity conductor, each with dimensions of 0.1×3×10 cm (width×length×height) were designed and built. tests were carried out in various condi...

Several low cost biomaterials such as rice husk, sugar cane bagasse, Tulsi Leaf &branches, coconut shell & coir and fly ash were tested for removal of chromium. All the experiments were carried out in batch process. The adsorbent, which had highest chromium (VI) removal, was coconut shell. An influence of chromium concentration, contact time on removal of chromium from effluent was investigated...