The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro-acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa-hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(-) ion in the equatorial plane and one O atom from the trichloro-acetate ligand and one phenanthroline N ...

We measured $^{35}$Cl abundances in 52 M giants with metallicities between -0.5 $<$ [Fe/H] 0.12. Abundances and atmospheric parameters were derived using infrared spectra from CSHELL on the IRTF optical echelle spectra. Cl by fitting a H$^{35}$Cl molecular feature at 3.6985 $\mu$m synthetic also of O, Ca, Ti, Fe atomic absorption lines. find that [Cl/Fe] ratio for our stars agrees chemical evol...

In the title complex, [Ni(C(11)H(16)N(3)O)]Cl·2H(2)O, the Ni(II) ion is coordinated within a distorted square-planar environment. In the crystal, inter-molecular N-H⋯Cl, N-H⋯O, O-H⋯O, O-H⋯Cl and weak C-H⋯O hydrogen bonds link the components into a two-dimensional network parallel to (001).

The ligand 3-chloro-6-dipicolylamino-1,2,4,5-tetrazine (Cl-TTZ-dipica) , prepared by the direct reaction between 3,6-dichloro-1,2,4,5-tetrazine and di(2-picolyl)-amine, afforded a series of four neutral transition metal complexes formulated as [Cl-TTZ-dipica-MCl2]2, with M = Zn(II), Cd(II), Mn(II) and Co(II), when reacted with the corresponding metal chlorides. The dinuclear structure of the is...

A tridentate benzoxazole-containing aminophenol ligand HL(BAP) was synthesized and complexed with Cu(II). The resulting Cu(II) complexes were characterized by X-ray, IR, UV-vis-NIR spectroscopies, and magnetic susceptibility studies, demonstrating that the ligand is oxidized to the o-iminosemiquinone form [L(BIS)](-) in the isolated complexes. L(BIS)Cu(II)Cl exhibits a distorted tetrahedral geo...

Since nitric oxide (NO) participates in the renal regulation of blood pressure, in part, by modulating transport of Na⁺ and Cl⁻ in the kidney, we asked whether NO regulates net Cl⁻ flux (JCl) in the cortical collecting duct (CCD) and determined the transporter(s) that mediate NO-sensitive Cl⁻ absorption. Cl⁻ absorption was measured in CCDs perfused in vitro that were taken from aldosterone-trea...

Delivery agents which can carry the {Ru(NO)}(6) chromophore ("caged NO") are desired for vasodilation and for photodynamic therapy of tumors. Toward these goals, complexes derived from [RuCl(3)(NO)(H(2)O)(2)]= (1) have been prepared using dipyridylamine (dpaH) as mono and bis adducts, [Ru(NO)Cl(3)(dpaH)] = (2) and [Ru(NO)Cl(dpaH)(2)]Cl(2) = (3). The dpaH ligands coordinate cis to the Ru(NO) axi...

In the title compound, (C(10)H(24)N)(2)[Cu(2)Cl(6)], N,N-diisopropyl-butanamine is protonated on the N atom. The Cu(II) atom in the centrosymmetric [Cu(2)Cl(6)](2-) anion has a distorted tetra-hedral geometry. In the crystal, the cations and anions are connected by N-H⋯Cl and C-H⋯Cl hydrogen bonds into layers parallel to (100).

Three new series of homoleptic and heteroleptic platinum(II) β-oxodithiocinnamic ester complexes, [Pt(L1–L9)2], [Pt(L1–L9)(DMS)Cl] [Pt(L1–L9)(DMSO)Cl], were synthesized characterized using elemental analysis, mass spectrometry, different NMR spectroscopy (1H, 13C{1H} 195Pt). The esters coordinate towards the centre as O,S-bidentate chelating ligands. structures HL3, [Pt(L2)2], [Pt(L6)(DMS)Cl] w...