نتایج جستجو برای: classical transition state
تعداد نتایج: 1232531 فیلتر نتایج به سال:
The Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semi-classical) radiation. The transition between the 1s ground state and the 2p0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R. The...
High-spin systems with orbital degeneracy are studied in the large spin limit. In the absence of Hund's coupling, the classical spin model is mapped onto disconnected orbital systems with spins up and down, respectively. The ground state of the isotropic model is an orbital valence bond state where each bond is an orbital singlet with parallel spins, and neighboring bonds interact antiferromagn...
abstract: two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (h2l5), and 1,10-phenanthroline(phen) and 1,3-di(4-pyridyl)propane (bpp) as secondary ligands are reported. they are formulated as {[pb(hl5)2(phen)(h2o)]·h2o}n(1), [zn2(hl5)4(bpp)2]n(2). all the complexes are characterized by single-crystal x-ray diffractions. compoud 1 crystallizes in the triclini...
Viewed as approximations to quantum mechanics, classical evolutions can violate the positive semidefiniteness of the density matrix. The nature of the violation suggests a classification of dynamical systems based on classical-quantum correspondence; we show that this can be used to identify when environmental interaction (decoherence) will be unsuccessful in inducing the quantum-classical tran...
The theory of scale relativity provides a new insight into the origin of fundamental laws in physics. Its application to microphysics allows us to recover quantum mechanics as mechanics on a non-differentiable (fractal) spacetime. The Schrödinger and Klein–Gordon equations are demonstrated as geodesic equations in this framework. A development of the intrinsic properties of this theory, using t...
We elucidate the basic physical mechanisms responsible for the quantum-classical transition in one-dimensional, bounded chaotic systems subject to unconditioned environmental interactions. We show that such a transition occurs due to the dual role of noise in regularizing the semiclassical Wigner function and averaging over fine structures in classical phase space. The results are interpreted i...
We analyze the quantum-to-classical transition QCT for coupled bipartite quantum systems for which the position of one of the two subsystems is continuously monitored. We obtain the surprising result that the QCT can emerge concomitantly with the presence of highly entangled states in the bipartite system. Furthermore, the changing degree of entanglement is associated with the backaction of the...
We investigate the classical limit of the dynamics of a semiclassical system that represents the interaction between matter and a given field. On using as a quantifier the qComplexity, we find that it describes appropriately the quantum-classical transition, detecting the most salient details of the changeover. Additionally the q-Complexity results a better quantifier of the problem than the q-...
We show that a special entropic quantifier, called the statistical complexity, becomes maximal at the transition between super-Poisson and sub-Poisson regimes. This acquires important connotations given the fact that these regimes are usually associated with, respectively, classical and quantum processes.
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