نتایج جستجو برای: classical transition state

تعداد نتایج: 1232531  

2008
C. Colijn E. R. Vrscay

The Bohm causal theory of quantum mechanics with spin-dependence is used to determine electron trajectories when a hydrogen atom is subjected to (semi-classical) radiation. The transition between the 1s ground state and the 2p0 state is examined. It is found that transitions can be identified along Bohm trajectories. The trajectories lie on invariant hyperboloid surfaces of revolution in R. The...

Journal: :Physical review letters 2002
Shun-Qing Shen X C Xie F C Zhang

High-spin systems with orbital degeneracy are studied in the large spin limit. In the absence of Hund's coupling, the classical spin model is mapped onto disconnected orbital systems with spins up and down, respectively. The ground state of the isotropic model is an orbital valence bond state where each bond is an orbital singlet with parallel spins, and neighboring bonds interact antiferromagn...

Journal: :inorganic chemistry research 2015
kai-fei wu yu feng fen jiang xian-li bai xian-hong yin

abstract: two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (h2l5), and 1,10-phenanthroline(phen) and 1,3-di(4-pyridyl)propane (bpp) as secondary ligands are reported. they are formulated as {[pb(hl5)2(phen)(h2o)]·h2o}n(1), [zn2(hl5)4(bpp)2]n(2). all the complexes are characterized by single-crystal x-ray diffractions. compoud 1 crystallizes in the triclini...

Journal: :Physical review letters 2002
Salman Habib Kurt Jacobs Hideo Mabuchi Robert Ryne Kosuke Shizume Bala Sundaram

Viewed as approximations to quantum mechanics, classical evolutions can violate the positive semidefiniteness of the density matrix. The nature of the violation suggests a classification of dynamical systems based on classical-quantum correspondence; we show that this can be used to identify when environmental interaction (decoherence) will be unsuccessful in inducing the quantum-classical tran...

2003
Marie-Noëlle Célérier Laurent Nottale L Nottale

The theory of scale relativity provides a new insight into the origin of fundamental laws in physics. Its application to microphysics allows us to recover quantum mechanics as mechanics on a non-differentiable (fractal) spacetime. The Schrödinger and Klein–Gordon equations are demonstrated as geodesic equations in this framework. A development of the intrinsic properties of this theory, using t...

Journal: :Physical review. E, Statistical, nonlinear, and soft matter physics 2007
Benjamin D Greenbaum Salman Habib Kosuke Shizume Bala Sundaram

We elucidate the basic physical mechanisms responsible for the quantum-classical transition in one-dimensional, bounded chaotic systems subject to unconditioned environmental interactions. We show that such a transition occurs due to the dual role of noise in regularizing the semiclassical Wigner function and averaging over fine structures in classical phase space. The results are interpreted i...

2005
Shohini Ghose Paul M. Alsing Barry C. Sanders Ivan H. Deutsch

We analyze the quantum-to-classical transition QCT for coupled bipartite quantum systems for which the position of one of the two subsystems is continuously monitored. We obtain the surprising result that the QCT can emerge concomitantly with the presence of highly entangled states in the bipartite system. Furthermore, the changing degree of entanglement is associated with the backaction of the...

Journal: :Entropy 2009
Andres M. Kowalski Angelo Plastino Montserrat Casas

We investigate the classical limit of the dynamics of a semiclassical system that represents the interaction between matter and a given field. On using as a quantifier the qComplexity, we find that it describes appropriately the quantum-classical transition, detecting the most salient details of the changeover. Additionally the q-Complexity results a better quantifier of the problem than the q-...

Journal: :Entropy 2014
Flavia Pennini Angelo Plastino

We show that a special entropic quantifier, called the statistical complexity, becomes maximal at the transition between super-Poisson and sub-Poisson regimes. This acquires important connotations given the fact that these regimes are usually associated with, respectively, classical and quantum processes.

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