our main objective is a better understanding of spin spin interaction of dinuclear copper(ii) complexes through  system. the synthesis and characterization of two new dinuclear copper(ii) complexes, based on the use of large, pyrole-containing macrocycles, the so called “ expanded porphyrins” , [cu2(macrocycle)]4+ is described. a chloroform solution spectrum of two complexes taken at room tem...

3-(2-Furanyl)-2-propenoic acid has been used to prepare a new series of organotin complexes of general formula R3SnL (R=Me, Et, n-Bu, Ph and Cy) and R2SnL2 (R=Me and n-Bu). These complexes have been characterized by elemental analyses, IR, 1H-NMR, MASS and Mössbaure spectroscopy.

The mode of coordination of8 manganese(fI), cobaltm, nickel(H), copper(II), zinc(H), lead(II) and cadmium(I1) to sodium ascorbate (NaHAsc) was investigated using IR, UV-visible, AAS, elemental microanalyzer, conductivity, magnetic and 'M and I3C NMR spectroscopic studies, NaNAsc is bidentate and coordination was through the carbonyl group and the oxygen atom of carbon-2 enolic hydfoxyl grou...

The interaction between eriochrome black T and Li , Na , K ,Mg and Ca ions in acetone and dimethylsulphoxide solutions has been investigated spectrophotometrically. The formation constants of the resulting 1 : 1 complexes were determined and found to decrease in the order Mg >Ca >Li >K >Na in both solvents used. There is an inverse relationship between the stabilities of the complexes...

the complexation reactions between diacetyl monooxime (damo), imidazole (him), histamine (hist) and histidine (his) with co2+, ni2+ and cu2+ were studied potentiometrically in aqueous solution at 25 °c and m= 0.5 m kno3. the overall stability constants log b's of species were obtained by computer refinement of ph-volume data using best computer program. several models were tested and, based on ...

electrochemical behavior of the new mono and dinuclear co (iii)  complexes of  the types trans-[pyco((do)(doh)pn )(l)]pf6   and [{py co((do)(doh)pn)}2 (μ-dicyd)] (pf6)2   have been studied in acetonitrile solution.  all the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to co(iii/ii)and  co(ii/i). each of these redox couples split to two  one electron  waves in...

1. introduction earthquake is a significant natural disaster which always affects different areas. zirkooh city due to the existence of active faults always faces destructive earthquakes (rajabi, 1384, p. 279). in may 9, 1997 this city was stricken by a severe earthquake with an intensity of 1.7 richter scale, and faced severe physical injuries, financial, and social damages. following the eart...

Five rare earth complexeslanthanum(III),praseodymium(III),neodymium(III), samarium(III) and europium(III) have been synthesized from Schiff base ligand (N,N-bis (2-hydroxy-1-naphthylidene) acetylhydrazone). The complexes were characterized based on elemental analysis, molar conductance, ultraviolet, infrared, mass, thermogravimetric and powder X-ray diffraction studies. Infrared spectra sug...

New diorganotin(IV) complexes of the type Ph2SnL2, Bu2SnL2 and Me2SnL2 of the ligands 2-thioacetic-5-phenyl-1,3,4-oxadiazole (HL1) and benzamidophenylalanine (HL2). Have been synthesized and characterized by physico-chemical techniques such as (elemental analysis, and electrolytic conductance) and spectr...