We present herein the compression mechanisms of linear 1,ω-diammonium-alkanes, confined within a molecular cage self-assembled in water. The exact coiling behaviour is determined from atomic resolution X-ray diffraction and shows crenel-like conformations in the compressed states.

objective(s):  although several chemical and physical methods for gene delivery have been introduced, their cytotoxicity, non-specific immune responses and the lack of biodegradability remain the main issues. in this study, hydroxyapatite nanoparticles (nps) and 1,2-dioleoyl-sn-glycero-3-phosphoethanol​amine (dope)-modified hydroxyapatite nps was coated with antisense oligonucleotide of e6 mrna...

background and aims: in this lab trial, the effect of scaffold based on human serum albumin (hsa) and hydroxyapatite nanoparticles (ha nps) on mouse spermatogonial cell line (scl) was investigated. materials and methods: to synthesize ha nps, calcium nitrate and diammonium phosphate at ph 13 were gently added and heated at 100 ºc for 24 hours. then serial concentrations of ha nps was separately...

A cover crop management trial in butternut squash was planted at the Forgotten Harvest Ore Creek Farm (9153 Major Rd, Fenton, MI 438430) in a Miami loam soil with a 02% grade. The objectives were to determine how yields following a cereal rye cover crop were affected by three tillage systems and three at-plant fertilizer treatments in a split-plot Randomized Complete Block Design with four repl...

Objective: The objective of the study was to develop and evaluate the reverse phase ultra-performance liquid chromatography (RP-UPLC) method for the quantitative determination of potential impurities of rivaroxaban active pharmaceutical ingredient. Method: The method uses a water acquity BEH C8 column (100mm x 2.1 mm, 1.7μm) with mobile phase A consisted, 0.05M diammonium hydrogen phosphate, pH...

Mead is an alcoholic beverage, produced since ancient times, resulting from an alcoholic fermentation of diluted honey by yeasts. When it is produced in a traditional manner, mead producers can encounter several problems related to a lack of essential nutrients, such as available nitrogen. Thus, the aim of this study was to evaluate the effect of nitrogen addition to honey-must on the fermentat...

Many methods for calcium estimation by flame spectrophotometry have been described. Investigations of biological material have dealt chiefly with plasma (Baker, 1955; Chen and Toribara, 1953; Denson, 1954; Kingsley and Schaffert, 1953; Llaurado, 1954; Maclntyre, 1954; Mosher et al., 1951; Rothe and Sapirstein, 1955; Winer and Kuhns, 1953; Zak et al., 1953), with application to urine in some cas...

The title compound, C(8)H(14)N(2) (2+)·C(12)H(8)N(2)O(8)P(-)·ClO(4) (-), was formed by the reaction of α,α-bis-m-xylenediamine and sodium bis-p-nitro-phenyl-phosphate in the presence of Zn(ClO(4))·6H(2)O in methanol solution. The two amine groups of the m-xylenediammonium ion are each protonated and each hydrogen-bonded to two O atoms of the phosphate anion, which acts as a 1,3-bridge. The ammo...

Evidence for the role of silica in plants is reviewed with respect to the application of silicate based sprays in biodynamic agriculture. There is research indicating improved resistance to pests, disease, drought and other stresses on plants from application of silica fertilisers and sprays. There is also evidence of improved nutrient uptake. Experiments with field grown lettuce were undertake...

A range of soil amendments including diammonium phosphate fertilizer (DAP), municipal biosolids (BS), biosolids compost, and Al- and Fe-based water treatment residuals were tested on Pb-, Zn-, and Cd-contaminated yard soils and tailings at the Tar Creek NPL site in Oklahoma to determine if amendments could restore a vegetative cover and reduce metal availability in situ. For the yard soils, all...