A magnetic solid-phase extraction (MSPE) method based on a novel magnetic sorbent was proposed for the extraction of target compounds from large-volume water samples. First, magnetic hypercrosslinked microspheres (NAND-1) were prepared via membrane emulsification-suspension polymerization and post crosslinking reaction. To ensure that the Fe3O4 nanoparticles could completely pass through the me...

BACKGROUND This proof-of-principle study examines whether postnatal, low-dose exposure to environmental chemicals modifies the composition of gut microbiome. Three chemicals that are widely used in personal care products-diethyl phthalate (DEP), methylparaben (MPB), triclosan (TCS)-and their mixture (MIX) were administered at doses comparable to human exposure to Sprague-Dawley rats from birth ...

Hydrothermally and sol-gel-synthesized immobilized surfactant-modified polyaniline-carbon nanotubes/TiO₂ (PANi-CNT/TiO₂) photocatalysts were prepared and their application in the degradation of diethyl phthalate (DEP) under visible light at 410 nm was investigated in this sturdy. To improve the dispersion of nanoparticles and the transfer of electrons, the TiO₂ surface was modified with both so...

Phthalate esters (PEs) are important environmental pollutants. While the biodegradation of the parent compound, phthalate (PTH), is well characterized, the biodegradation of PEs is not well understood. In particular, prior to this study, genes involved in the uptake and hydrolysis of these compounds were not conclusively identified. We found that Rhodococcus jostii RHA1 could grow on a variety ...

Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric loss at a fixed frequency using a microregulator in which temperature is controlled by means of a Peltier element. Compared to conventional equipment, the n...

Plasticiser loss, a fundamental mechanism in the degradation of polymeric materials, leads to material instability and contamination environment. The process depends on environmental conditions, but size container which an object is housed thickness also play key roles rate plasticiser loss time at equilibrium reached. Understanding these dependencies provides valuable insight into plastic muse...

Phthalic acid esters (phthalates) are used as plasticizers in numerous consumer products, commodities, and building materials. Consequently, phthalates are found in human residential and occupational environments in high concentrations, both in air and in dust. Phthalates are also ubiquitous food and environmental contaminants. An increasing number of studies sampling human urine reveal the ubi...

A new molecularly imprinted mesoporous material (MIM) containing specific pockets for the extraction of diethyl phthalate (DEP) as copper complex has been prepared for the first time. The mesoporous material was developed by utilizing copper-phthalate complex (Cu-DEP) as the template molecule, 3-aminopropyltriethoxysilane (APS) as a functional monomer and tetraethoxyorthosilicate (TEOS) as the ...

Detection and characterization of the presence of chemical agent aerosols in various complex atmospheric environments is an essential defense mission. Raman spectroscopy has the ability to identify chemical molecules, but there are limited numbers of photons detectable from single airborne aerosol particles as they are flowing through a detection system. In this paper, we report on a single-par...