electrochemical behavior of the new mono and dinuclear co (iii)  complexes of  the types trans-[pyco((do)(doh)pn )(l)]pf6   and [{py co((do)(doh)pn)}2 (μ-dicyd)] (pf6)2   have been studied in acetonitrile solution.  all the  mono nuclear complexes  show two quasi- reversible reduction couples associate  to co(iii/ii)and  co(ii/i). each of these redox couples split to two  one electron  waves in...

New dinuclear MII-LnIII complexes of general formulas [Cu(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN·H2O (LnIII = Gd (1), Tb (2), Dy (3) and Er (4)), [Ni(CH3CN)(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN Nd (5), (6), (7), (8), (9) Y (10)) [Co(CH3CN)(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN (11), (12), (13), (14) (15)) were prepared from the compartmental ligand N,N?-dimethyl-N,N?-bis(2-hydroxy-3-formyl-5-bromo-benzyl)ethylenediamine (H2L)....