an efficient, rapid, simple, and highly selective dispersive liquid–liquid microextraction basedon solidification of floating organic drop (dllme-sfod), combined with flame atomicabsorption spectrometry was developed for preconcentration and determination of trace amountsof cobalt in water samples. in this method, an appropriate mixture of acetone and1-undecanol was injected rapidly into the aq...

The widespread use of perfluoroalkyl substances (PFAS) is resulting in a broad human exposure to these endocrine disrupting chemicals (EDCs), prompting biomonitoring research evaluate its magnitude and impact, especially during critical windows such as fetal perinatal periods. This study was focused on developing method determine 10 PFAS placental tissue by combining salt-assisted liquid-liquid...

an air–assisted liquid–liquid microextraction method for the extraction and preconcentration of trace amounts of some synthetic phenolic antioxidants in biological fluids followed by their determination by gas chromatography–flame ionization detection has been reported. in this method the target analytes are extracted into a few microliters of carbon tetrachloride (extraction solvent) from an a...

Dispersive liquid-liquid microextraction (DLLME) coupled with gas chromatography-mass spectrometry (GC-MS) has been developed for preconcentration and determination of tramadol, ((±)-cis-2-[(dimethylamino)methyl]-1-(3-methoxyphenyl)cyclohexanol-HCl), in aqueous and biological samples (urine, blood). DLLME is a simple, rapid and efficient method for determination of drugs in aqueous samples. Eff...

An efficient and environmentally friendly sample preparation method based on the application of hydrophobic 1-Hexylpyridinium hexafluorophosphate [Hpy][PF(6)] ionic liquid (IL) as a microextraction solvent was proposed to preconcentrate terazosin. The performance of the microextraction method was improved by introducing a common ion of pyridinium IL into the sample solution. Due to the presence...

Polycyclic aromatic hydrocarbons (PAHs) are classified as persistent and carcinogenic organic pollutants. PAHs contamination has been reported in water. Many of relevant regulatory bodies such as EU and EPA have regulated the limit levels for PAHs in drinking water. In this study, 13 priority polycyclic aromatic hydrocarbons (PAHs) were determined in tap water samples of Tehran and water for in...

In this research paper, a simple and economic ionic liquid-based liquid-liquid microextraction (IL-DLLME) procedure was developed to ensure efficient rapid separation preconcentration of erythrosine from cosmetic food samples. Important parameters such as IL volume, temperature, acetone ultrasonic time pH that may affect the IL-DLLME have been optimized by central composite design (CCD) based o...