Abstract Tree-derived dissolved organic matter (DOM) comprises a significant carbon flux within forested watersheds. Few studies have assessed the optical properties of tree-derived DOM. To increase understanding factors controlling DOM quality, we measured properties, (DOC) and calcium concentrations in throughfall stemflow for 17 individual rain events during summer fall temperate deciduous f...

We compute by numerical transfer-matrix methods the surface free energy τ(T ), the surface stiffness coefficient κ(T ), and the single-step free energy s(T ) for Ising ferromagnets with (∞×L) square-lattice and (∞×L×M) cubic-lattice geometries, into which an interface is introduced by imposing antiperiodic or plus/minus boundary conditions in one transverse direction. The surface tension σ(θ, T...

On any set X may be defined the free algebra R〈X〉 (respectively, free commutative algebra R[X]) with coefficients in a ring R. It may also be equivalently described as the algebra of the free monoid X∗ (respectively, free commutative monoid M (X)). Furthermore, the algebra of differential polynomials R{X} with variables inX may be constructed. The main objective of this contribution is to provi...

We compute the finite-size corrections to the free energy, internal energy and specific heat of the critical two-dimensional spin-1/2 Ising model on a triangular and hexagonal lattices wrapped on a torus. We find the general form of the finite-size corrections to these quantities, as well as explicit formulas for the first coefficients of each expansion. We analyze the implications of these fin...

In nanofluidic devices, nonuniform confinement induces an entropic force that automatically drives biopolymers toward less-confined regions to gain entropy. To understand this phenomenon, we first analyze the diffusion of an entropy-driven particle system. The derived Fokker-Planck equation reveals an effective driving force as the negative gradient of the free energy. The derivation also shows...

Free energy potentials, combining molecular mechanics with empirical solvation and entropic terms, are used to discriminate native and near-native protein conformations from slightly misfolded decoys. Since the functional forms of these potentials vary within the field, it is of interest to determine the contributions of individual free energy terms and their combinations to the discriminative ...

The finite-temperature Casimir free energy, entropy, and internal energy are considered anew for a conventional parallel-plate configuration, in the light of current discussions in the literature. In the case of an "ideal" metal, characterized by a refractive index equal to infinity for all frequencies, we recover, via a somewhat unconventional method, conventional results for the temperature d...

Nomenclature H AW adiabatic wall enthalpy (J/kg) H w wall enthalpy (J/kg) H 0 total enthalpy (J/kg) h heat transfer coefficient (kg/m 2 /sec), h FR reference Fay-Riddell heat transfer coefficient (kg/m 2 /sec) L model reference length (m) M ∞ free stream Mach number q FR reference Fay-Riddell heat transfer rate (W/m 2) Re ∞ free stream unit Reynolds number (1/m) T ∞ free stream temperature (K) ...

In the context of the SAMPL5 challenge water-cyclohexane distribution coefficients for 53 drug-like molecules were predicted. Four different models based on molecular dynamics free energy calculations were tested. All models initially assumed only one chemical state present in aqueous or organic phases. Model A is based on results from an alchemical annihilation scheme; model B adds a long rang...