In this work, an extensive study on the glass transition temperature (Tg), dynamic fragility and activation energy (Ea) for a variety polymeric nanocomposite materials, based four different types of matrices reinforced with carbonaceous nanofillers, SiO2 has been performed. Referring to mechanical analysis data obtained in author's previous works, were calculated examined. Depending type, behav...

We propose that embedding silicon nanoparticles (NP) into amorphous, nonstoichiometric ZnS leads to promising nanocomposites for solar energy conversion. Using ab initio molecular dynamics simulations we show that, upon high temperature amorphization of the host chalcogenide, sulfur atoms are drawn to the NP surface. We find that the sulfur content may be engineered to form a type II heterojunc...

Structural characterisations using the SAXS technique in a number of nanoheterogeneous materials and liquid solutions are reviewed. The studied systems are protein (lysozyme)/water solutions, colloidal ZnO particles/water sols, nanoporous NiO-based xerogels, hybrid organic-inorganic siloxane-PEG and PPG nanocomposites and PbTe semiconductor nanocrystals embedded in a glass matrix. These investi...

chitosan (chito) as a biopolymer with high antibacterial, biocompatibility and biodegradability and polyaniline (pani) as a conductive polymer and silver (ag) nanoparticles to enhance antibacterial property were used to prepare polyanilin-chitosan-silver (pani-chito-ag) nanocomposites. the synthesis of panichito composite and pani-chito-ag nanocomposite was performed through aniline polymerizat...

Cardiovascular disease claims millions of lives every year throughout the world. Biomaterials are used widely for the treatment of this fatal disease. With the advent of nanotechnology, the use of nanocomposites has become almost inevitable in the field of biomaterials. The versatile properties of nanocomposites, such as improved durability and biocompatibility, make them an ideal choice for va...

New monolithic nanocomposite silica biomaterials were synthesized on the basis of various natural polysaccharides and recently introduced completely water-soluble precursor tetrakis(2-hydroxyethyl) orthosilicate. The sol-gel processes were performed in aqueous solutions without the addition of organic solvents and catalysts. The silica polymerization was promoted by the polysaccharides through ...

For many important applications, the performance of polymer-anisotropic particle nanocomposite materials strongly depends on the orientation of the nanoparticles. Using the very peculiar magnetic properties of goethite (α-FeOOH) nanorods, we produced goethite-poly(hydroxyethyl methacrylate) nanocomposites in which the alignment direction and the level of orientation of the nanorods could easily...

This review describes the present state of science and technology of photopolymerizable (UV-curable) polyurethane (PU) nanocomposites which include nanosilica and organically-modified clay (organoclay). A number of documented improvements of properties of PU nanocomposites compared to the pristine PU are presented. Many data on the structure and properties of PU nanocomposites were obtained not...

A series of hybrid cadmium salt/cationic surfactant layered nanocomposites containing different concentrations of cadmium sulphide was prepared by exchanging chloride by sulphide ions in the layered precursor CdXx(OH)y(CnTA)z in a solid phase/gas reaction, resulting in a series of layered species exhibiting stoichiometries corresponding to CdSvXx(OH)y(CnTA)z, constituted by two-dimensional CdCl...

An overview of the progress in polymer nanocomposites is presented in this paper with an emphasis on the different methods used for preparing polymer-layered silicate (PLS) nanocomposites and the extent to which properties are enhanced. Other related areas that are also discussed include the types of polymers used in PLS nanocomposites preparation, the types of PLS nanocomposites morphologies t...