Dedicated to Professor Alfred Klemm on the occasion of his 70th birthday Electron, neutron and X-ray diffraction patterns of l iquid fo rmamide have been measured at a temperature of 25 °C. Analysis of the diffraction data yields the molecular structure and the average geometry of the hydrogen bond. The molecular parameters obtained from liquid diffraction experiments are in good agreement with...

The title compound, C(15)H(16)N(2)S, crystallizes with two molecules in the asymmetric unit. The crystallographic behaviour of the two isomers is different. The mol-ecules are dimerized, forming an R(2) (2)(8) ring motif due to inter-molecular N-H⋯S hydrogen bonds. C-H⋯S hydrogen bonds form R(2) (2)(12) ring motifs. In one molecule, the dihedral angle between the benzene rings is 62.54 (6)°, wh...

Hydrogen storage is required to make a breakthrough commercializing hydrogen energy; however, the development of material based on both physisorption and chemisorption faced their limit. To this end, researchers pay attention applying spillover mechanism storage, lot research report positive effect introduction Pt dissociate molecule into porous performance. Moreover, migration adsorption disso...

A study has been made of t he reactions of lithium aluminum hydride with methyl bromide, methylene chloride, meth ylene bromide, methylene iodide, chloroform, bromoform, and carbon t etrachloride. Except for hydrogen and unreacted h alida, essentia lly pure methane was formed in each case. The amount of hydrogen evolved increased with the n umber of halogen atoms in the molecule, reaching a max...