Abstract Efficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range high yields under mild conditions. In addition, (3+3) cycloaddition between oxyallyl cation precursor and hydroxylamine was als...

A single-step method for aniline formation was examined. Using a vanadate catalyst with an iron oxide co-catalyst and hydroxylamine hydrochloride as the amine source, up to 90% yield of obtained high selectivity. Further study showed that overall reaction pseudo-second order in terms concentration. Regioselective H-D exchange experiments suggest C-N bond step occurs via irreversible electrophil...