A simple method for the determination of volatile selenium compounds employing a gas chromatograph equipped with a photoionization detector is described. The method involves the direct injection of dimethylselenide (DMS) or dimethyldiselenide (DMDS) into the gas chromatograph; no derivatization of the sample was required. The photoionization detector was capable of detecting 60 pg (0.55 pmol) o...

The world's rare selenium resources need to be managed carefully. Selenium is extracted as a by-product of copper mining and there are no deposits that can be mined for selenium alone. Selenium has unique properties as a semi-conductor, making it of special value to industry, but it is also an essential nutrient for humans and animals and may promote plant growth and quality. Selenium deficienc...

This review deals with liquid phase separation of major arsenic and selenium species followed by element specific detection. It concerns papers published since 1980 and describing only currently used methods that were or could be applied to As and Se speciation in environmental matrices. Methods performances are compared on the basis of efficiency, rapidity, absolute and concentration detection...

The effect of selenium supplementation in inorganic and organic form was investigated in three five-member groups of ewes and their lambs in the course of 7 months. The basal feed ration contained 55 μg Se, ewes of experimental group E1 received a supplement of 180 μg Se in sodium selenite, and ewes of experimental group E2 were applied a supplement of 180 μg selenium bound in the biomass of th...

Selenium (Se) is placed in Group VIA of the Periodic Table. Its chemistry is similar to sulfur (S). Practically all small organic selenium compounds are isologues of corresponding sulfur compounds. With a few exceptions, they are also isologues of sulfur amino acids or derivatives thereof. Selenium plays an indispensable role for humans, animals and microorganisms. It is beneficial for the meta...