A set of enantiomerically pure cyclic multinuclear complexes with the formula cis-[a(2)PdL](n) (n+) [a(2)=(R,R)-1,2-diaminocyclohexane (R,R-dach), (S,S)-1,2-diaminocyclohexane (S,S-dach); n=4, 6; LH=2-hydroxypyrimidine (2-Hpymo), 4,6-dimethyl-2-hydroxypyrimidine (2-Hdmpymo) and 4-hydroxypyrimidine (4-Hpymo)] were obtained by reaction of cis-[a(2)Pd(H(2)O)(2)](2+) and LH in aqueous media. The po...

The structural properties of micelles formed by the non-ionic surfactant, Triton X-114 (TX-114), were investigated using all-atom molecular dynamics (MD) simulations. Additionally, we effect solubilisation sodium salts two nonsteroidal anti-inflammatory drugs, ibuprofen and indomethacin, upon TX-114 micelles. micelle in absence drugs has an aspherical shape. We find that as continues to solubil...

Currently a new version of the distance education platform WeLearn [3] to be combined with an agent system ([1], also developed locally) for providing advanced services [2] is under development. In a previous stage of the project software was created to automatically derive keywords from documents, either from the different versions of metadata already contained (various Microsoft file formats,...

As our ability to store information increases, the mechanisms we employ to access that information become ever more important. In this paper, we present Archosum, a prototype of an organizational system that attempts to encapsulate the benefits of both hierarchical and keyword systems. By introducing abstract entities, Archosum provides a simple interface with which users can build and maintain...

ODUCTION ar sensors with dual-polarization capability etter understanding and characterization of hazards. Advanced knowledge-based hazard algorithms would require better knowledge of ttering characteristics of hydrometeors such as , hailstones, and snowflakes. Especially, characteristics becomes important for utilize phase-array dual-polarization radar Traditionally, theoretical approaches [1]...

Au-nanoclusters between 2 and 8 nm in diameter were deposited onto solid substrates in different pattern geometries. The basis of this approach is the self-assembly of polystyrene-b-poly[2-vinylpyridine (HAuCl4)] diblock copolymer micelles into uniform monomicellar films on solid supports such as Si-wafers or glass cover slips. HAuCl4 as metallic precursor or a single solid Au-nanoparticle caus...

Hybrid polyion complex (HPIC) micelles are nanoaggregates obtained by complexation of multivalent metal ions by double hydrophilic block copolymers (DHBC). Solutions of DHBC such as the poly(acrylic acid)-block-poly(acrylamide) (PAA-b-PAM) or poly(acrylic acid)-block-poly(2-hydroxyethylacrylate) (PAA-b-PHEA), constituted of an ionizable complexing block and a neutral stabilizing block, were mix...

We describe a method for generating sentences from “keywords” or “headwords”. This method consists of two main parts, candidate-text construction and evaluation. The construction part generates text sentences in the form of dependency trees by using complementary information to replace information that is missing because of a “knowledge gap” and other missing function words to generate natural ...

Our atomistic molecular dynamics simulations reveal the existence of bound and free water molecules in the hydration layer of an aqueous micelle. The bound water molecules can be either singly or doubly hydrogen bonded to the polar head group on the surface of the micelle. The ratio of bound to free water is found to be approximately equal to 9:1 at 300 K. email:[email protected] email:bbagchi@...