Great efforts of the scientific community are focused on development catalysts for reduction carbon dioxide (CO2) to useful molecules such as monoxide, formic acid, methanol, ethanol, methane, ethylene, or acetate. Various metal porphyrin complexes were synthesized and studied develop highly active selective catalysts. While substituents core (the primary coordination sphere) determine reactivi...

One of the major factors, contributing to the emission of greenhouse gases in the environment is generation of pollutant gases in municipal landfills. As for the design and building of a gas collecting system, it is necessary to properly estimate the amount and type of the landfill emissions. By means of LandGEM model, this study predicts the amount and type of the landfill gases, produced for ...

the role of nickel as catalyst on the conversion of methane and ethylene in a gas phase flow reactor in the absence of oxygen is studied. in this study, nickel in its different forms is used as catalyst. the role of pressure, flow rate, and temperature on the conversion of feed gases is investigated. the experiments have been carried out in the presence and absence of the catalysts to measure t...

An alumina-supported nickel catalyst was prepared by impregnation of Ni2+ solution onto mesoporous alumina under microwave irradiation (denoted as M-Ni/Al2O3). For comparison, a catalyst with the same nickel content was prepared by conventional impregnation method (denoted as UM-Ni/Al2O3). Both M-Ni/Al2O3 and UM-Ni/Al2O3 catalysts were applied to the syngas (H2 + CO) production by methane oxy-s...

there is strong evidence demonstrating that nifedipine dissolved in ethanol selectively inhibits only l-type ca2+ current. in addition, acute ethanol exposure reduces voltage-dependent calcium currents. in the present study, we investigated the antagonistic effect of fixed concentration of nifedipine dissolved in different concentration of ethanol on l-type ca2+ current. in a na+-k+ free soluti...

Abstract:  In this study, the change in the crystalline structure of gas hydrate was predicted for ternary mixture of methane-ethane-water. For this purpose, the tangent plane distance (TPD) minimization method was used. First, the calculations were performed for the binary mixtures of methane-water and ethane-water as the gas and liquid phases. The results show that for a binary mixture of th...

abstract: â in this study, the change in the crystalline structure of gas hydrate was predicted for ternary mixture of methane-ethane-water. for this purpose, the tangent plane distance (tpd) minimization method was used. first, the calculations were performed for the binary mixtures of methane-water and ethane-water as the gas and liquid phases. the results show that for a binary mixture of th...

copper trimesate (cu-btc) mof has been pointed out as a promising adsorbent for separating carbon dioxide from methane. however, mof’s need to be shaped prior to their use in packed bed adsorbers in order to reduce pressure drop; on the other hand, the production of mechanically resistant shaped bodies reduces their adsorption performance. in this work, cu-btc tablets provided by basf are evalu...