نتایج جستجو برای: n disubstituted diaminoglyoxime

تعداد نتایج: 978854  

Journal: :Advanced Synthesis & Catalysis 2021

N-Activated ketimines are characterized by the presence of acyl, sulfonyl, and phosphinoyl groups linked to nitrogen atom azomethine system. These electron-withdrawing enhance electrophilic character imino moiety allowing addition even weak nucleophilic reagents. The oxygen atoms in these activating with its coordinating Lewis or Brønsted properties is paramount importance asymmetric catalyzed ...

Ali Kakanejadifard, Golamreza Najafi S. Morteza Farnia

The one pot reaction of glyoxal and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of diaminoglyoxime. By increasing stoichiometric ratio of the hydroxylamine hydrochloride and decreasing the solvent volume, the product yield increased considerably (~ 70%).

A facile and one-pot multicomponent synthesis of novel 1,4-disubstituted-1H-1,2,3-triazoles from alkenes at room temperature is reported. At the first step, in the presence of I2/NaN3 reagents, various alkenes were converted to the corresponding azido iodides and in the next step, the reaction of these compounds with phenylacetylene in the presence of catalytic amount of sodium ascorbate/ CuSO4...

Journal: :Chemistry 2011
Ying Duan Mu-Wang Chen Zhi-Shi Ye Duo-Sheng Wang Qing-An Chen Yong-Gui Zhou

Tandem reactions and consecutive catalysis (or relay catalysis) have been receiving considerable attention in organic synthesis due to their abilities of constructing multiple new chemical bonds to build complex chiral molecules in a single operation. Transition-metal-catalyzed asymmetric hydrogenation is one of the most widely used and reliable catalytic methods for preparation of chiral molec...

2017
Heng Luo Yu-Fen Xia Bao-Fei Sun Li-Rong Huang Xing-Hui Wang Hua-Yong Lou Xu-Hui Zhu Wei-Dong Pan Xiao-Dong Zhang

To get inside the properties of N,N-disubstituted Schiff bases, we synthesized three high-yielding benzaldehyde Schiff bases. We used the reaction between salicylaldehyde and different diamine compounds, including diamine, ethanediamine, and o-phenylenediamine, determining the structure of obtained molecules by nuclear magnetic resonance spectroscopy and electrospray ionization mass spectroscop...

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