The development of a Ni(II) (S)-Tol-BINAP-catalyzed enantioselective alkylation of N-acylthiazolidinethiones with trimethyl orthoformate is described. The reaction is general with respect to the thiazolidinethione, providing the desired adducts in good to excellent yield and with high levels of enantioselectivity (11 examples, 51-92% yield, 90-99% ee). The products are readily converted into a ...

A convenient, efficient and practical procedure for the synthesis of 1-amidoalkyl 2-naphthols is described by condensation of aromatic aldehydes with amides and 2-naphthol in the presence of P2O5/SiO2 as an efficient catalyst. Moreover, in the present of this catalyst, the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes is studied by co...

a new kinetic spectrophotometic method for the determination of trace amount chromium (iii) in teareal samples has been described based on it s the catalytic effect on the oxidations of 1 - ( 2 –pyridylazo ) - 2 - naphthol, (pan), by potassium bromated in sulfuric acid. the reaction is followedspec- trophotometrically by measuring the decrease in the absorbance at 469 nm. under the optimumcondi...

In this work, Fe3O4@nano-walnut shell/BIII (FNWSB), as a reusable and new catalyst was prepared then characterized by FT-IR, XRD, FESEM, EDS-MAP, TGA. This used for synthesis of tetrahydrobenzo[a]xanthen-11-ones via three-component, one-pot condensation reaction dimedone, β-naphthol, aromatic aldehydes. An uncomplicated work-up, high yields product, short times, use low-cost are considerable ad...

A convenient, efficient and practical procedure for the synthesis of 1-amidoalkyl 2-naphthols is described by condensation of aromatic aldehydes with amides and 2-naphthol in the presence of P2O5/SiO2 as an efficient catalyst. Moreover, in the present of this catalyst, the synthesis of 14-aryl or alkyl-14H-dibenzo[a,j]xanthenes is studied by co...

peptide synthesis. Enzymatic peptide synthesis is more advantageous than chemical synthesis since the enzymatic method is stereoselective and is secure from racemization. There are, however, several problems to be solved with this method. Secondary hydrolysis of the resulting peptide may arise from the inherent nature of the protease. Moreover, the method is limited to the use of amino acid der...

melamine trisulfonic acid (mtsa) is utilized as a highly efficient catalyst for the solvent-free condensation reaction of 2-naphthol (2 eq.) with arylaldehydes (1 eq.) under conventional thermal as well as microwave conditions to give the d

In short-term organ cultures of normal human peripheral lung, phenolic substrates are metabolized predominantly to sulphate ester conjugates with little or no glucuronic acid conjugates being formed (Mehta & Cohen, 1979). However, with shortterm organ culture of tumour tissue from the lung of the same patients, the converse appears true (R. Mehta & G. M. Cohen, unpublished work). The rationale ...