A synthesis of the 2-phosphathioethynolate anion, PCS-, under ambient conditions is reported. The coordination chemistry of PCO-, PCS- and their nitrogen-containing congeners is also explored. Photolysis of a solution of W(CO)6 in the presence of PCO- [or a simple ligand displacement reaction using W(CO)5(MeCN)] affords [W(CO)5(PCO)]- (1). The cyanate and thiocyanate analogues, [W(CO)5(NCO)]- (...

Two-electron reductive carbonylation of the uranium(VI) nitride [U(Tren(TIPS))(N)] (2, Tren(TIPS)=N(CH2CH2NSiiPr3)3) with CO gave the uranium(IV) cyanate [U(Tren(TIPS))(NCO)] (3). KC8 reduction of 3 resulted in cyanate dissociation to give [U(Tren(TIPS))] (4) and KNCO, or cyanate retention in [U(Tren(TIPS))(NCO)][K(B15C5)2] (5, B15C5=benzo-15-crown-5 ether) with B15C5. Complexes 5 and 4 and KNC...

The RADARs use complex techniques such as stagger PRI, jitter PRI with frequency agile characteristics. The frequency agile RADARs switch frequencies with in a pulse to get different types of advantages. Today lot of RADAR signal processing takes place on FPGA platform. These signal processing algorithms include pulse parameters estimation, deinterleaving of mixed pulse patterns, processing com...

To clarify the physiological role of calcium-activated neutral protease (CANP) in human platelets, we loaded the platelets with a Ca2+ -sensitive fluorescent dye, fura-2, and measured the degree of aggregation, cytosolic calcium ion concentration [( Ca2+]i), and proteolysis by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). At physiological concentration of Ca2+ (1 mM) in ...

During meiosis programmed DNA double-strand breaks (DSBs) are repaired by homologous recombination using the sister chromatid or the homologous chromosome (homolog) as a template. This repair results in crossover (CO) and non-crossover (NCO) recombinants. Only CO formation between homologs provides the physical linkages guiding correct chromosome segregation, which are essential to produce heal...

In addition to the ATP-binding cassette (ABC)-type nitrate/nitrite-bispecific transporter, which has a high affinity for both substrates (K(m), approximately 1 microM), Synechococcus elongatus has an active nitrite transport system with an apparent K(m) (NO(2)(-)) value of 20 microM. We found that this activity depends on the cynABD genes, which encode a putative cyanate (NCO(-)) ABC-type trans...