Field ionization of trimethylamine and of N,N-dimethylaniline doped into xenon is presented as a function of xenon number density up to the density of the triple point liquid, both at noncritical temperatures and along the critical isotherm. These data exhibit a decrease in the xenon induced shift of the dopant ionization energy near the xenon critical point. The energy of the quasi-free electr...

The adsorption behavior of chlorendic acid (1, 4, 5, 6, 7, 7-hexachlorobicyclo-(2, 2, 1) -hept-5-ene-2, 3dicarboxylic acid) onto hydrophilic fumed TiO2 (P-25, Degussa) in aqueous suspension was investigated. Results indicate that chlorendic acid adsorbed strongly in short times (2-5 mins) onto TiO2. Adsorption data is consistent with LangmuirHinshelwood isotherm model for monolayer adsorption a...

Specific surface area is an important property of porous materials and a crucial index in multiple disciplines, which mainly measured using nitrogen isotherms the Brunauer–Emmett-Teller (BET) equation. The BET remarkably higher than geometric area, defined as crystal geometry structure. However, many studies directly use area. We proposed simple, general, accurate method that only needs adsorpt...

introduction: biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. also, living lichens are known to accumulate metals across their surface. materials and methods: in this study, the biosorption of cadmium ions cd (ii) by the lichens acarospora strigata, lecanora muralis and caloplaca aurantia was investigated in aqueous solution in...

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...

Using grand canonical Monte Carlo simulation we show, for the first time, the influence of the carbon porosity and surface oxidation on the parameters of the Dubinin-Astakhov (DA) adsorption isotherm equation. We conclude that upon carbon surface oxidation, the adsorption decreases for all carbons studied. Moreover, the parameters of the DA model depend on the number of surface oxygen groups. T...

The ability of coconut husk to remove methylene blue from solution was investigated. Factors such as initial dye concentration, contact time, adsorbent dosage and pH of solution were studied. Results show that Langmuir isotherm can be successfully applied to the methylede blue coconut husk system and that coconut husk is a suitable adsorbent for such a dye. Maximum adsorption capacity is 99 mg ...