The concentrations and removal efficiencies of various kinds of micropollutants were investigated and the relationships between the input sources of industrial wastewater and occurrence patterns of each micropollutant were identified at nine on-site industrial wastewater treatment plants (WWTPs). The distribution pattern of each compound varied according to the WWTP type and several micropollut...

To characterize the eel contamination by dioxin-like (dl) and non dioxin-like (ndl) polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs), sixty-two eels from the Loire estuary (France) were analyzed. PCB contamination significantly increased from glass eel stage (3.71 ± 1.85 and 15.2 ± 4.2 ng g(-1) dw) to other life stages (for yellow eels: 62.8 ± 34.4 and...

Old agrochemical samples were analyzed for their dioxin impurities. Some herbicides were contaminated with 2,3,7,8-chlorine-substituted dioxin congeners. Using these new data as well as impurity and emission data reported in the literature, the time trends for dioxin emissions from the use of chlorinated aromatic compounds and some incineration activities have been estimated. The results indica...

Dioxin levels measured after wet scrubbing systems have been found to be higher than levels measured before the scrubber. It is believed that there is an adsorption of PCDD/Fs on plastic materials in the scrubber. The PCDD/F levels after a polishing wet scrubber were followed continuously for 18 months using long-time sampling equipment at a hazardous waste incineration facility in Sweden. Each...

This study presents a detailed mechanistic account of the formation of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) from polychlorinated diphenyl ethers (PCDEs). It applies the recently developed meta hybrid M06-2X functional and deploys the 2,2'-dichlorodiphenylether (2,2'-DCDE) molecule as a representative model compound for all PCDEs congeners. We find that, ...

Aerobic aromatic-hydrocarbon-degrading bacteria from a semi-anaerobic microbial microcosm that exhibited apparent complete dechlorination of polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDD/Fs) were isolated through enrichment and plating culture procedures with dibenzofuran as the model substrate. By 16S rRNA gene sequence comparisons, these dibenzofuran-degrading isolates were identified...

This work presents the results of a short-term natural detoxification experiment carried out with the contaminated Manila clam (Tapes philippinarum), an edible bivalve species subjected to intense exploitation in the Venice Lagoon. The concentrations of seventeen PCDD/F congeners and twelve dioxin-like PCBs were determined in sediments as well as T. philippinarum specimen sampled in a lagoon ar...

Freely dissolved and gas phase polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were measured in the water column and atmosphere at five locations within Newark Bay (New Jersey, USA) from May 2008 to August 2009 with polyethylene (PE) passive samplers. Mono- to octa-CDDs and mono- to hepta-CDFs were detected in bottom and surface waters at ≤ 20 pg/L with no cl...

Earlier surveys indicate that meat, fish and dairy products are the principal source of polychlorinated dibenzo-p-dioxin (PCDD) exposure in the diet. A recent finding by others of PCDDs in chickens that consumed a feed containing PCDD led to the finding of ball clay, an anti-caking agent, as the source. Supercritical fluid extraction (SFE) was studied as a means to isolate PCDDs from commercial...