Perovskite-related Cs4PbBr6 nanocrystals present a "zero-dimensional" crystalline structure where adjacent [PbBr6]4- octahedra do not share any corners. We show in this work that these nanocrystals can be converted into "three-dimensional" CsPbBr3 perovskites by extraction of CsBr. This conversion drastically changes the optoelectronic properties of the nanocrystals that become highly photolumi...

This paper presents the accumulation process of radioactive Cs in edible mushrooms. We here first report the direct accumulation pathway of radioactive Cs from contaminated wood logs to the fruit-bodies of shiitake mushrooms through the basal portion of the stipe. In this pathway, radioactive Cs is not transported through the hyphae. This pathway results in a high accumulation of radioactive Cs...

Here we report the derivatization of mesoporous TiO2 thin films for the preparation of H2O2 amperometric sensors. The coordination of the bifunctional ligand 1,10 phenantroline, 5,6 dione on the surface Ti(IV) ions provides open coordination sites for Fe(II) cations which are the starting point for the growth of a layer of Prussian blue polymer. The porous structure of the mesoporous TiO2 allow...

A one-step synthesis of Prussian blue nanoparticles possessing a concentration gradient of Gd3+ counterions, g-Gd-PB, has been developed, and the potential for the particles to perform as both MRI positive contrast agents and photothermal therapy agents is demonstrated. The synthesis of potassium/gadolinium ironhexacyanoferrate is performed under increasing concentration of Gd3+ ions forming pa...

Carbon film resistor electrodes have been evaluated as transducers for the development of multiple oxidase-based enzyme electrode biosensors. The resistor electrodes were first modified with Prussian Blue (PB) and then covered by a layer of covalently immobilized enzyme. Electrochemical impedance spectroscopy was used to characterize the interfacial behaviour of the Prussian Blue modified and e...

The reduction of ferricyanide ions in alkaline solution followed by formation of Prussian blue (ferric ferrocyanide), which is measured quantitatively, has been the basis of a method for the estimation of blood sugar (1). This method has been modified several times (2-6). Though the reduction reaction suffers from lack of specificity, the convenience and sensitivity of the procedure often make ...

Aim Silver nanoparticles have long been used as potent antibacterial agents. However, toxicity concerns of silver nanoparticles have limited their successful clinical applications. Hence, development of silver-based novel biocompatible nanomaterials for antibacterial applications is a challenging task. Materials & methods Accordingly, in this work, we synthesized a biocompatible silver-based ...

Edged plane pyrolytic graphite electrode (EPPGE) was modified with and without Prussian blue (PB) nanoparticles and polyaminobenzene sulphonated single-walled carbon nanotubes (SWCNTPABS) using the chemical deposition method. The electrodes were characterised using microscopy, spectroscopy and electrochemical techniques. Results showed that edged plane pyrolytic graphite-single-walled carbon na...

Greenhouse experiments were carried out to evaluate the effect of different soil-based countermeasures on radiocesium transfer to Medicago saliva (alfalfa) grown on artificially contaminated loamy-clayey soil. Various rates of potassium, ammonium, and Prussian Blue supplements were applied, and the uptake of radiocesium by control and treated alfalfa plants was monitored during four growth peri...

Three-dimensional Prussian blue-reduced graphene oxide hydrogel was synthesized with the assistance of sodium dodecyl sulfate (SDS) through a facile hydrothermal method. The hydrogel exhibited strong mechanical properties and was successfully applied as a self-propelling motor for water treatment. During the self-propelling degradation process, SDS facilitated the rapid liberation of oxygen bub...