......................................................................................................................................... ii Acknowledgements ................................................................................................................... iv List of Tables ............................................................................................................

Asymmetric zinc porphyrin (ZnPy) was synthesized and used to sensitize nanosized TiO2. The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase was observed from the ZnPy-sensitized TiO2 without loading noble metal, and the mechanism was discussed.

This paper reviews the recent development of surface-reaction-limited pulsed chemical vapor deposition (SPCVD) technique for the growth of TiO2 one-dimensional nanostructures. SPCVD uses separated TiCl4 and H2O precursor pulses, and the anisotropic growth of TiO2 crystals is attributed to the combined effects of surface recombination and HCl restructuring at high temperature during elongated pu...

The interfacial structure of water in contact with TiO2 is the key to understand the mechanism of photocatalytic water dissociation as well as photoinduced superhydrophilicity. We investigate the interfacial molecular structure of water at the surface of anatase TiO2, using phase-sensitive sum frequency generation spectroscopy together with spectra simulation using ab initio molecular dynamic t...

Two-step thermal oxidation was proposed for Ti and Ti alloys as a surface-treatment process for preparing an anatase-containing TiO2 layer. This process consisted of treatment in a CO-containing atmosphere (first step) and subsequent treatment in air (second step). In this chapter, first, the current status of TiO2 coating onto Ti and Ti alloys for biomedical applications is reviewed; then our ...

Vanadium dioxide (VO2) is a Mott phase transition compound that can be applied as a thermochromic smart material for energy saving and comfort, and titanium dioxide (TiO2) is a well-known photocatalyst for self-cleaning coatings. In this paper, we report a VO2@TiO2 core-shell structure, in which the VO2 nanorod core exhibits a remarkable modulation ability for solar infrared light, and the TiO2...

Fruit and vegetable containers with microbe-free surfaces can be made by coating with titanium dioxide (TiO2) particles or nonmetal (C, N, B, F) doped-TiO2 particles, using wear resistant polymers, such as zein, and paint, as the binders and to form a continuous binding phase. The doped-TiO2 powders absorb visible light radiation, and thus possess a higher antibacterial effect than non-modified...

The principal purpose of this study is to present a new design for preparing highly active immobilized gold nanoparticle-based plasmonic photocatalysts. Gold nanoparticles were loaded on rutile TiO2 particles with a mean size of 80 nm (Au/TiO2) by the deposition precipitation method. The surface of SnO2 particles with a mean size of 100 nm was modified by copper(ii) oxide clusters (CuO/SnO2) wi...

The surface properties of TiO2-PVDF nanocomposite membranes were investigated by incorporating different chemically modified TiO2 nanoparticles into the poly (vinylidene fluoride) (PVDF) matrix. The nanocomposite membranes were prepared via dual coagulation bath diffusion and the induced phase inversion method. The membrane surface morphologies were investigated by using SEM and AFM and related...