We report on a novel theory and experiment for scanning electrochemical microscopy (SECM) to enable quasi-steady-state voltammetry of rapid electron transfer (ET) reactions at macroscopic substrates. With this powerful approach, the substrate potential is cycled widely across the formal potential of a redox couple while the reactant or product of a substrate reaction is amperometrically detecte...

The effect of core geometry constraints hydrogenase H-cluster analogues on reduction chemistry have been explored by a combination structural, electrochemical and IR spectroelectrochemical (IR-SEC) studies. A series phosphido-bridged diiron hexacarbonyl complexes, Fe2(µ2-PPh2(CH2)xPPh2)(CO)6, x = 2 (2P) 4 (4P) previously reported with 3 (3P) the unlinked bis-diphenylphosphido (DP) were investig...

The oxygen electrode with a fast reduction reaction (ORR), evolution (OER), and sufficient durability plays pivotal role in reversible solid oxide cells (RSOCs). Here, we d...

A quantum-dot cellular automata(QCA) is important technology to be with CMOS. QCA is expected to reach very high operating frequencies and significant reduction of power consumption. Reversible logic is an one-to-one mapping between the input and output vectors. Reversible logic is significant in QCA circuit with almost zero power dissipation. In this paper we propose a new reversible gate usin...

In this work, we study the integrability of quotients quasi-Poisson manifolds. Our approach allows us to put several classical results about Poisson in a common framework. By categorifying one already known methods reducing symplectic groupoids also describe double groupoids, which integrate recently introduced groupoid structures on gauge groupoids.