Structural study of Khosrow Parviz silver coins present in the museum Bu Ali Sina tomb using X-ray fluorescence spectroscopy method

A tetraphenylethene (TPE)-decorated tripodal tris(urea) ligand was synthesized, which shows large emission enhancement when binding to an orthophosphate anion (PO4(3-)), but exhibits only weak or no fluorescence with other anions. The anion-binding and fluorescence properties were studied by X-ray crystal structure, NMR and fluorescence spectroscopy, and by DFT computations and the results demo...

X-ray absorption spectral (XAS) analysis is performed with a combination of a 9 V dry electric battery X-ray generator and a portable Si PIN X-ray detector. The calcium K edge (4.0 keV) in paper is measured with a grazing incidence geometry, which suppressed the artifact due to the Kalpha X-ray fluorescence peak at 3.5 keV. The 9 V dry battery X-ray emitter is useful for portable XAS measurements.

The fluorescence detection of ultra high energy cosmic rays requires a detailed knowledge of the fluorescence light emission from nitrogen molecules over a wide range of atmospheric parameters, corresponding to altitudes typical of the cosmic ray shower development in the atmosphere. We have made a precise measurement of the fluorescence light spectrum excited by MeV electrons in air. The relat...

Stimuli-responsive luminescent materials, which are dependent on changes in physical molecular packing modes, have attracted more and more interest over the past ten years. In this study, 2,2-dihydroxy-1,1-naphthalazine was synthesized and shown to exhibit different fluorescence emission in solution and solid states with characteristic aggregation-induced emission (AIE) properties. A remarkable...

The XDD beamline (http://ssls.nus.edu.sg/facility/beamlines/xdd/xdd.htm) at SSLS delivers a tunable monochromatized photon source with high resolution in a wide energy range (2.3-10 keV). This hard x-ray light source is ideal for diffractometry, fluorescence detection and absorption spectroscopy, especially the study of XAFS (x-ray absorption fine structure) and XANES ( X-ray Absorption Near Ed...

S ORAL PRESENTATIONS X-ray Fluorescence microscopy and micro-spectroscopy: Multidisciplinary tools

Structure-activity relationships in heterogeneous catalysis are challenging to be measured on a single-particle level. For the first time, one X-ray beam is used to determine the crystallographic structure and reactivity of a single zeolite crystal. The method generates μm-resolved X-ray diffraction (μ-XRD) and X-ray excited optical fluorescence (μ-XEOF) maps of the crystallinity and Brønsted r...

This paper presents a portable total reflection X-ray fluorescence system composed of a 15 W X-ray tube, with a gold anode, a waveguide constituted by two Perspex(®) parallel plates, a Si PIN detector and a quartz optical flat. The critical angle of the total reflection system was experimentally determined by measuring a zinc solution (100 mg/L). The accuracy of the system was checked using SRM...