We report a simple but powerful method for engineering multi-walled carbon nanotubes (MWNTs) by using manipulation by an atomic-force microscope. The successive shell-by-shell extraction process of ultralong MWNTs allows the exposure of the innermost single-walled carbon nanotubes (SWNTs), which have diameters as small as approximately 0.4 nm. The inner-shell extraction process changes the elec...

A new immunoassay with biotinylated single-walled carbon nanotubes as persistent, non-photobleaching Raman biomarkers demonstrated excellent sensitivity and specificity.

The size-dependent metal to nonmetal transition in metal nanoparticles has been investigated using photoelectron and tunneling spectroscopic techniques. Metal nanoparticles capped by thiols are shown to organize into ordered 2D and 3D structures. Single-walled nanotubes and aligned carbon nanotube bundles have been synthesized by controlling the size of metal nanoparticles produced in situ duri...

Single-walled carbon nanotubes can be readily wrapped in and dispersed by long single-stranded DNA molecules (ssDNAs) synthesized by rolling circle amplification.

One-step diameter-selective dispersion of HiPco single-walled carbon nanotubes has been accomplished through noncovalent complexation of the nanotubes with a water-soluble, biocompatible polymer chitosan at room temperature.

Vertically aligned single-walled carbon nanotube arrays were synthesized from dip-coated binary Co/Mo catalyst by no-flow chemical vapor deposition from either pure ethanol or acetonitrile as carbon feedstock. By changing to acetonitrile the mean diameter was reduced from 2.1 nm to less than 1.0 nm despite using identically prepared catalyst. The demonstrated diameter control on flat substrates...

The electrochemistry of banana tissues on a carbon paste electrode modified with multi-walled carbon nanotubes (MWCNTs) is presented. Cyclic voltammetry is applied to investigate the direct electrochemistry of banana tissues i.e. a source of polyphenol oxidase (PPO). A redox couple with an anodic and counterpart cathodic peak is obtained. The influence of various parameters such as pH,...

We present near-field Raman spectroscopy and imaging of single isolated single-walled carbon nanotubes with a spatial resolution of approximately 25 nm. The near-field origin of the image contrast is confirmed by the measured dependence of the Raman scattering signal on tip-sample distance and the unique polarization properties. The method is used to study local variations in the Raman spectrum...

adsorbed natural gas has various advantages and is relatively more economical than liquefaction and compression. carbon nanotubes can be introduced as a new candidate for natural gas storage. in this study, adsorption of methane was firstly studied on the as-prepared multi-walled carbon nanotubes, and then chemical and physical treatment of mwcnts was performed to enhance the methane adsorption...

in this paper, the chemical functionalization of carboxylate multi-walled carbon nanotubes by methyl (triphenyl phosphoranylidene) acetate have been investigated. phosphorus ylides are important compound in organic chemistry. at first, methyl (triphenyl phosphoranylidene) acetate, synthesized from salt metod in two steps: the formation of the phosphonium salt and the deprotonation of the latter...