نتایج جستجو برای: singlet triplet energy gaps

تعداد نتایج: 733339  

2010
Congjun Wu

The symmetry properties of the Cooper pairing problem for multicomponent ultracold dipolar molecular systems are investigated. The dipolar anisotropy provides a natural and robust mechanism for both triplet and singlet Cooper pairing to first order in the interaction strength. With a purely dipolar interaction, the triplet pz-like polar pairing is the most dominant. A short-range attractive int...

H. Rabani

In this paper, we calculate theoretically the relaxation rates of hot, thermal and antinodal quasiparticles by using Fermi’s golden rule. The transition probabilities at low temperatures express in terms of Bogoliubov coefficients, singlet and triplet scattering amplitudes and dimensionless Landau parameters. The values of Landau parameters may be determined by comparison with the experimental ...

Journal: :The Journal of chemical physics 2008
M Alducin H F Busnengo R Díez Muiño

We study the dissociative dynamics of O(2) molecules on the Ag(100) surface. Initially, the impinging molecules are either in the spin-triplet ground state or in the spin-singlet excited state. The molecule-surface interaction is obtained in each case by constructing the six-dimensional potential energy surface (PES) from the interpolation of the energies calculated with spin-polarized and non-...

2000
Allan L. L. East Edward C. Lim

Computations have been performed for the singlet and triplet electronic states of varying orientations of naphthalene dimer. The dependence of exciton splitting upon orientation and intermonomer distance was explored. Splittings of triplet states are seen to be nontrivial at typical bonding distances, commensurate with the splittings of weakly allowed singlet states. Charge-transfer interaction...

2003
W. B. Zeimen G. C. Groenenboom A. van der Avoird

The dissociating states of the triplet–excited CO–He complex are studied by means of scattering calculations on ab initio diabatic potential energy surfaces produced in the preceding paper ~Paper I!. With the aid of an effective transition dipole function and the bound states of the CO–He complex in the ground singlet state we obtain the photoabsorption cross section as a function of the excita...

Journal: :Physical review letters 2003
A S Dhoot N C Greenham

The triplet to singlet exciton formation ratio in a MEH-PPV light-emitting diode is measured by comparing the triplet-induced absorptions with optical and electric excitations at the same singlet exciton density. The ratio is a strong universal decreasing function of the averaged electric field. Using 4 ns for singlet to triplet intersystem crossing time, the ratio is significantly larger than ...

Journal: :Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 2015
F Deng A J Francis W W Weare F N Castellano

Non-coherent sensitized red-to-green upconversion has been achieved utilizing platinum(II) tetraphenyltetrabenzoporphyrin (PtTPTBP) as the triplet sensitizer and a nearly quantitatively fluorescent meso-(2,6-dichloropyridyl)-substituted boron dipyrromethene (Cl2PyBODIPY) chromophore (Φ = 0.99 in toluene) as the energy acceptor/annihilator in deoxygenated toluene. Dynamic Stern-Volmer analysis r...

2015
Hironori Kaji Hajime Suzuki Tatsuya Fukushima Katsuyuki Shizu Katsuaki Suzuki Shosei Kubo Takeshi Komino Hajime Oiwa Furitsu Suzuki Atsushi Wakamiya Yasujiro Murata Chihaya Adachi

Efficient organic light-emitting diodes have been developed using emitters containing rare metals, such as platinum and iridium complexes. However, there is an urgent need to develop emitters composed of more abundant materials. Here we show a thermally activated delayed fluorescence material for organic light-emitting diodes, which realizes both approximately 100% photoluminescence quantum yie...

2010
P. E. Kornilovitch

We compute the properties of singlet and triplet bipolarons on two-dimensional lattices using the continuous time quantum Monte Carlo algorithm. Properties of the bipolaron including the total energy, inverse mass, bipolaron radius and number of phonons associated with the bipolaron demonstrate the qualitative difference between models of electron phonon interaction with longrange interaction (...

Journal: :Philosophical transactions. Series A, Mathematical, physical, and engineering sciences 2015
Andrew Monkman Richard H Friend

Organic electronics now supports a rapidly growing industry, including organic light-emitting diode (OLED) displays as used in cell phone displays and upmarket TVs. This has been enabled both by successful engineering of materials and devices, and also through the design of new device architectures that allow control of electron spin. This is a rapidly moving field, and some recent advances in ...

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