Using the ARGUS detector at the e+e storage ring DORIS II, we have measured the Michel parameters , , and for ! l  decays in -pair events produced at center of mass energies in the region of the resonances. Using ! as spin analyzing tags, we nd e = 0:68 0:04 0:08, e = 1:12 0:20 0:09, e = 0:57 0:14 0:07, = 0:69 0:06 0:08, = 1:25 0:27 0:14 and = 0:72 0:18 0:10. In addition, we report the combine...

In the presence of nuisance parameters, we derive an explicit higher order asymptotic formula to compare the expected lengths of conndence intervals given by likelihood ratio statistics arising from the usual proole likelihood and various adjustments thereof. Highest posterior density regions, with approximate frequentist validity, are also included in the study.

The solvatochromic responses of uric acid (Ua), 6-amino-2-thiouracil (ATU) and a series of their complexes dissolved in ten solvents of different polarity have been measured. The solvent-dependent UV/Vis spectroscopic absorption maxima, λ(max), are assigned to the corresponding electronic transitions and analyzed using SPSS program, regression analysis and Kamlet and Taft methods. The observed ...

Intermolecular interactions regulate the molecular properties in proteins and solutions such as solvatochromic systems. Some of the interactions have to be described at an electronic-structure level. In this study, a commutator for calculating the excitation energy is used for deriving a first-order interacting space (FOIS) to describe the environmental response to solute excitation. The FOIS w...

We present the optical properties of fully (C42F28, PF-RUB) and half-fluorinated (C42F14H14; F14-RUB) rubrene, both in thin films and as monomers in solution and compare them to hydrogenated rubrene (C42H28, RUB). All three compounds show similar optical absorption bands and photoluminescence line shapes. The results are interpreted with density functional calculations of the orbital energies a...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

For hypotheses of the type H0 : θ = θ0 vs H1 : θ 6= θ0 we demonstrate the equivalence of a Bayesian hypothesis test using a Bayes factor and the corresponding classical test, for a large class of models, which are detailed in the paper. In particular, we show that the role of the prior and critical region for the Bayes factor test is only to specify the type I error. This is their only role sin...

A new series of solvatochromic binuclear mixed ligand complexes with the general formula: Cu2(DMCHD)(Am)2X3 (where, DMCHD: 5.5-Dimethyl cyclohexanate 1,3-dione, Am=N,N,N’-trimethylethylenediamine (Me3en), N,N,N’,N’tetramethylethylenediamine (Me4en), or N,N,N’,N’,N’’-penta-methyldiethylenetriamine (Me5dien) and X=ClO4or Clhave been synthesized and characterized by the analytical, spectral method...

Absorption spectra of three aminoazobenzene dyes with various molecular size and alkyl tails have been recorded in solvents in the range between 200 to 600 nm. The photophysical behavior of a dissolved dye depends on the nature of its environment, i.e. the intensity, shape, and maximum absorption wavelength of the absorption band of dye in solution depends strongly on the solvent-solute interac...